Collect. Czech. Chem. Commun. 1972, 37, 3456-3466
https://doi.org/10.1135/cccc19723456

Stereochemical studies. LXIX. Contribution of syn- and anti-elimination to the monosubstituted olefin formation from 1-decyltrimethylammonium base

M. Pánková, A. Vítek, S. Vašíčková, R. Řeřicha and J. Závada

Individual author index pages


Other CCCC articles of these authors

  • R. Řeřicha
    Parentage of the local excited electronic state of ethene coordinated in Zeise's salt
    1977, Vol. 42, Issue 12, pp. 3530–3538 [Abstract]
  • R. Řeřicha
    Zeise's anion as a system of strongly anharmonic coupled oscillators
    1977, Vol. 42, Issue 12, pp. 3518–3529 [Abstract]
  • M. Pánková and J. Závada
    Alkyl structure-reactivity relationships in anti-elimination of open-chain tosylates: On steric hindrance to approach of associated and dissociated tert-butoxide base
    1977, Vol. 42, Issue 12, pp. 3439–3448 [Abstract]
  • J. Závada and M. Pánková
    Alkyl structure-selectivity relationships E2 reactions of open-chain tosylates: Steric effects in the anti-pathway induced by dissociated and associated tert-butoxide base
    1977, Vol. 42, Issue 12, pp. 3421–3438 [Abstract]
  • Pavel Kočovský, V. Černý, S. Vašíčková and M. Synáčková
    Stereochemistry of some 5-methyl-19-nor-5β-cholest-9-ene derivatives
    1977, Vol. 42, Issue 11, pp. 3339–3353 [Abstract]
  • M. Pánková and J. Závada
    The effect of hydrogen bonding on orientation in anti-E2 reactions
    1977, Vol. 42, Issue 7, pp. 2161–2166 [Abstract]
  • M. Pánková and J. Závada
    Geometrical and positional orientation in anti-E2 reactions: The effect of base association in a wider scale of transition states
    1977, Vol. 42, Issue 6, pp. 1981–1991 [Abstract]
  • J. P. Girard, J. C. Rossi, R. Escale, S. Vašíčková and M. Tichý
    Conformational study of cyclic 2-amino and 2-dimethylamino alcohols with six-membered ring by 1H-NMR spectroscopy
    1977, Vol. 42, Issue 1, pp. 90–104 [Abstract]
  • J. Závada, M. Pánková and M. Svoboda
    syn-anti Duality in E2 reactions: The effects of leaving group and base association in the competing pathways
    1976, Vol. 41, Issue 12, pp. 3778–3798 [Abstract]
  • Š. Urban, M. Horák and A. Vítek
    Application of a general profile function to mathematic description and to separation of bands in the infrared spectrum of methanesulphonyl chloride
    1976, Vol. 41, Issue 12, pp. 3685–3690 [Abstract]
  • S. Vašíčková, A. Vítek, M. Tichý, J. P. Girard and J. C. Rossi
    Infrared study of chair-boat equilibria and deformations in derivatives of trans-bicyclo[4,3,0]nonane: A comparison with trans-decalin system
    1976, Vol. 41, Issue 12, pp. 3600–3606 [Abstract]
  • M. Streibl, S. Vašíčková, V. Herout and V. Bouška
    Chemical composition of cenomanian fossil resins from Moravia
    1976, Vol. 41, Issue 10, pp. 3138–3145 [Abstract]
  • J. Závada, M. Pánková and Z. Arnold
    Silver perchlorate promoted reactions: Arylmethylation of aromatics by bromomethylarenes
    1976, Vol. 41, Issue 6, pp. 1777–1790 [Abstract]
  • R. Řeřicha and P. Svoboda
    IR spectrum of the zwitterionic analogue of Zeise's salt, [H2C=CHCH2NH3(+)PtCl3(-)]
    1976, Vol. 41, Issue 4, pp. 1014–1023 [Abstract]
  • J. Souček, K. Stránský, R. Řeřicha and J. Hetflejš
    Separation of nongeminal divinylhexamethylcyclotetrasiloxanes
    1975, Vol. 40, Issue 9, pp. 2611–2615 [Abstract]
  • R. Řeřicha
    Re-interpretation of the vibrational spectra of Zeise's salt. The nature of the Pt-ethene bond
    1975, Vol. 40, Issue 9, pp. 2577–2591 [Abstract]
  • V. Benešová, Z. Samek and S. Vašíčková
    Structure of the sequiterpenic lactone diplophyllolide and other components from the liverwort Diplophyllum albicans (L.) DUM.
    1975, Vol. 40, Issue 6, pp. 1966–1970 [Abstract]
  • R. Řeřicha and J. Hetflejš
    Relation between the electronic spectra of free methylethenes and vibrational spectra of the methylethenes coordinated to platinum
    1975, Vol. 40, Issue 6, pp. 1811–1822 [Abstract]
  • M. Tichý and M. Pánková
    Diequatorial chair transition state in cyclisation of a diequatorial benzamido methanesulphonate
    1975, Vol. 40, Issue 3, pp. 647–657 [Abstract]
  • M. Pánková and M. Tichý
    Cyclisation of N-benzoyl-O-methanesulphonyl derivatives of conformationally biased diequatorial 2-aminocyclohexanols
    1975, Vol. 40, Issue 3, pp. 634–646 [Abstract]
  • J. Málek, M. Černý and R. Řeřicha
    Formation of anionic intermediates in the reduction and alkylation of anthracene and its derivatives by sodium bis(2-methoxyethoxy)aluminum hydride
    1974, Vol. 39, Issue 9, pp. 2656–2666 [Abstract]
  • R. Řeřicha and M. Čapka
    Vibronic problems in 1-decene-1,2-dx analogs of Zeise's salt
    1974, Vol. 39, Issue 8, pp. 2221–2233 [Abstract]
  • M. Pánková and M. Tichý
    Cyclisation and solvolysis of stereoisomeric 4-tert-butyl-2-aminomethylcyclohexanol derivatives
    1974, Vol. 39, Issue 6, pp. 1447–1461 [Abstract]
  • P. Svoboda, R. Řeřicha and J. Hetflejš
    Reactions of [(C6H5)3P]3RuCl2 with some silicon hydrides
    1974, Vol. 39, Issue 5, pp. 1324–1329 [Abstract]
  • R. Řeřicha, J. Štokr, M. Jakoubková, P. Svoboda and V. Chvalovský
    The vibrational spectra of vinylmethylhalosilanes H2C=CH(CH3)3-nSiXn (n = 1, 2; X = F, Cl)
    1974, Vol. 39, Issue 5, pp. 1303–1312 [Abstract]
  • M. Horák and A. Vítek
    Computerized assignment of the binary combination/overtone vibrational frequencies to infrared bands of monohalogeno benzenes
    1974, Vol. 39, Issue 5, pp. 1107–1117 [Abstract]
  • M. Tichý, L. Kniežo and S. Vašíčková
    Intramolecular hydrogen bonding in some vicinal derivatives of tricyclo[4,4,0,03,8]decane (twistane)
    1974, Vol. 39, Issue 2, pp. 555–565 [Abstract]
  • J. Jizba, S. Vašíčková and V. Herout
    Components of the fern Polypodium aureum L.
    1974, Vol. 39, Issue 2, pp. 501–505 [Abstract]
  • J. Smolíková, M. Havel, S. Vašíčková, A. Vítek, M. Svoboda and K. Bláha
    Conformation of 1-aza-2-cycloalkanones with large rings: Infrared spectroscopic study
    1974, Vol. 39, Issue 2, pp. 459–467 [Abstract]
  • A. Vítek
    New function describing the profiles of IR absorption bands
    1974, Vol. 39, Issue 2, pp. 366–368 [Abstract]
  • J. Smolíková, M. Havel, S. Vašíčková, A. Vítek, M. Svoboda and K. Bláha
    Conformation of medium ring lactams: Infrared spectroscopic study
    1974, Vol. 39, Issue 1, pp. 293–306 [Abstract]
  • M. Pánková, J. Krupička and J. Závada
    Rates of the Menschutkin reaction in alkyldimethylamines: The effect of alkyl structure and solvent
    1974, Vol. 39, Issue 1, pp. 167–170 [Abstract]
  • R. Řeřicha and M. Čapka
    Vibrational spectra of the trihalosilyl-1- or -2-butenes obtained by hydrosilylation
    1974, Vol. 39, Issue 1, pp. 144–153 [Abstract]
  • M. Mejstříková, R. Řeřicha and M. Kraus
    The nature of hydrosilylation catalyst from chloroplatinic acid and polystyrene substituted by dimethylaminomethyl groups
    1974, Vol. 39, Issue 1, pp. 135–143 [Abstract]
  • J. Závada, M. Pánková and M. Svoboda
    Stereochemical studies. LXXIV. The alkyl structure-reactivity relationship in Cope elimination of alkyldimethylamine oxides
    1973, Vol. 38, Issue 7, pp. 2102–2120 [Abstract]
  • S. Vašíčková, A. Vítek and M. Tichý
    Stereochemical studies. LXXIII. Conformational equilibria in 3-hydroxypiperidine and in some of its methyl derivatives
    1973, Vol. 38, Issue 6, pp. 1791–1803 [Abstract]
  • J. Smolíková, A. Vítek and K. Bláha
    Amino acids and peptides. CXI. Conformational dependence of the stretching vibration of the N-H bond in trans-amides
    1973, Vol. 38, Issue 2, pp. 548–558 [Abstract]
  • Z. Arnold, J. Kahovcová, M. Pánková, M. Svoboda, M. Tichý and F. Šorm
    Natural and synthetic materials with the insect hormone activity. XIV. Synthesis of substituted phenyl geranyl ethers and related compounds
    1973, Vol. 38, Issue 1, pp. 261–269 [Abstract]
  • M. Svoboda and J. Závada
    Stereochemical studies. LXX. The role of base ion-pairing in bimolecular elimination: The effect of a base counterion on the steric course
    1972, Vol. 37, Issue 12, pp. 3902–3904 [Abstract]
  • P. Sedmera, A. Vítek and Z. Samek
    Computer construction of standard steroid models
    1972, Vol. 37, Issue 12, pp. 3828–3836 [Abstract]
  • R. Řeřicha, A. Vítek, S. Vašíčková, M. Pánková and J. Závada
    The infrared spectra of 1-decenes deuterated on the double bond. A comparison with the vinyl halides-dx
    1972, Vol. 37, Issue 11, pp. 3749–3761 [Abstract]
  • K. Waisser, M. Buděšínský, A. Vítek and A. Vystrčil
    Triterpenes. XXVII. Conformational analysis of the A-cycle of 1,3-dihydroxy derivatives of pentacyclic triterpenoids
    1972, Vol. 37, Issue 11, pp. 3652–3659 [Abstract]
  • F. Hanousek, B. Štíbr, S. Heřmánek, J. Plešek, A. Vítek and F. Haruda
    Chemistry of boranes. XXVI. Infrared spectra of monosubstituted decaboranes
    1972, Vol. 37, Issue 9, pp. 3001–3009 [Abstract]
  • J. Závada, M. Pánková and J. Sicher
    Stereochemical studies. LXIII. The contribution of syn- and anti-elimination to olefin formation in branched open-chain systems: The effect of alkyl structure on steric course of bimolecular elimination
    1972, Vol. 37, Issue 7, pp. 2414–2435 [Abstract]
  • R. Řeřicha
    The IR spectra of benzene and cyclohexane adsorbed on co-precipitated nickel-alumina aerogel
    1972, Vol. 37, Issue 5, pp. 1607–1621 [Abstract]
  • J. Sicher, M. Svoboda, M. Pánková and J. Závada
    Stereochemical studies. LXII. The Hofmann-Saytzeff and the syn-anti elimination dichotomy: A relationship between the two phenomena
    1971, Vol. 36, Issue 11, pp. 3633–3649 [Abstract]
  • J. Sicher, J. Závada and M. Pánková
    Stereochemical studies. LXI. The contribution of syn- and anti-elimination to olefin formation in open-chain systems: 5-Decyl and 5-nonyl trimethylammonium bases and tosylates
    1971, Vol. 36, Issue 9, pp. 3140–3164 [Abstract]
  • J. Sicher, M. Pánková, J. Závada, L. Kniežo and A. Orahovats
    Stereochemical studies. LX. Steric course of bimolecular elimination in bicyclo[2.2.2]octyl onium bases and tosylates
    1971, Vol. 36, Issue 9, pp. 3128–3139 [Abstract]
  • J. Smolíková, A. Vítek and K. Bláha
    Amino acids and peptides. CIII. Infrared spectra and conformations of methylamides of N-acylated amino acids with a hydroxyl group in the side chain
    1971, Vol. 36, Issue 7, pp. 2474–2485 [Abstract]
  • Z. Pacl, M. Jakoubková, R. Řeřicha and V. Chvalovský
    Organogermanium compounds. X. The effect of structure on the basicity of ethyl(dimethylamino)germanes
    1971, Vol. 36, Issue 6, pp. 2181–2188 [Abstract]
  • M. Tichý, S. Vašíčková, A. Vítek and J. Sicher
    Stereochemical studies. LIX. Flattened chair and twist-boat conformations in cis-2-dimethylaminocyclohexanols
    1971, Vol. 36, Issue 4, pp. 1436–1447 [Abstract]
  • R. Řeřicha and Z. Šír
    Vacuum polarographic investigation of air oxygen dissolved in ethylene glycol
    1971, Vol. 36, Issue 2, pp. 664–673 [Abstract]
  • M. Horák, J. Pitrová, R. Řeřicha and V. Horák
    Molecular structure diagnosis with the use of infrared spectroscopy and computer applied to dialkyl sulphides
    1970, Vol. 35, Issue 11, pp. 3223–3229 [Abstract]
  • M. Tichý, S. Vašíčková, S. V. Arakelian and J. Sicher
    Stereochemical studies. LVII. Conformational equilibria in trans-2-amino- and trans-2-dimethylaminocyclohexanols: Evaluation of the gauche interactions between OH and NR2
    1970, Vol. 35, Issue 5, pp. 1522–1535 [Abstract]
  • R. Řeřicha and K. Kochloefl
    The infrared spectra of alicyclic secondary alcohols adsorbed on γ-alumina industrial catalyst
    1969, Vol. 34, Issue 1, pp. 206–211 [Abstract]
  • J. Závada, M. Svoboda and J. Sicher
    Stereochemical studies. LIII. Steric course of cycloalkyl 'onium base eliminations: Direct evidence for the syn-anti elimination dichotomy using deuterium labelled cyclodecyl derivatives
    1968, Vol. 33, Issue 12, pp. 4027–4038 [Abstract]
  • A. Vítek
    A general method for the computation of redundant internal coordinates in cyclic molecules
    1968, Vol. 33, Issue 5, pp. 1601–1604 [Abstract]
  • J. Sicher, M. Tichý, J. Závada and J. Krupička
    Stereochemical studies. LII. Rates of the Menschutkin reaction in cyclohexyldimethylamines. Some unusual rate effects in a simple reaction
    1968, Vol. 33, Issue 5, pp. 1438–1450 [Abstract]
  • M. Havel, J. Krupička, M. Svoboda, J. Závada and J. Sicher
    Stereochemical studies. LI. Effect of ring size on the rates of quaternization of the N-methylazacycloalkanes
    1968, Vol. 33, Issue 5, pp. 1429–1437 [Abstract]
  • M. Svoboda, J. Závada and J. Sicher
    Stereochemical studies. L. The mechanism of bimolecular elimination of cycloalkyl tosylates. The scope of syn-elimination: Dependence on reaction conditions and substrate structure
    1968, Vol. 33, Issue 5, pp. 1415–1428 [Abstract]
  • J. Závada, J. Krupička and J. Sicher
    Stereochemical studies. IL. The mechanism of cycloalkene formation from cycloalkyl bromides. The scope of the syn-anti bimolecular elimination dichotomy
    1968, Vol. 33, Issue 5, pp. 1393–1414 [Abstract]
  • J. Sicher and J. Závada
    Stereochemical studies. XLVIII. Effect of base and solvent on the steric course and mechanism of cycloalkene formation in 'onium salt eliminations
    1968, Vol. 33, Issue 4, pp. 1278–1293 [Abstract]
  • R. Řeřicha and M. Horák
    Determination of the degree of branching in alkanes by infrared spectroscopy. III. Analytical application
    1968, Vol. 33, Issue 2, pp. 496–505 [Abstract]
  • J. Závada and J. Sicher
    Stereochemical studies. XLIV. The syn-anti elimination dichotomy - A general feature in cycloalkene formation from 'onium salts in protic solvents
    1967, Vol. 32, Issue 10, pp. 3701–3712 [Abstract]
  • J. Krupička and J. Závada
    Polarography of cycloalkyldimethylamine oxides. A polarographic method for the kinetic study of the amine oxide elimination reaction (Cope elimination)
    1967, Vol. 32, Issue 8, pp. 2797–2808 [Abstract]
  • J. Sicher and J. Závada
    Stereochemical studies. XLII. The effect of ring size on the rate of formation of cis- and trans-cycloalkenes from cycloalkyltrimethylammonium salts: Evidence on the simultaneous operation of syn- and anti-mechanisms in bimolecular elimination
    1967, Vol. 32, Issue 6, pp. 2122–2133 [Abstract]
  • M. Svoboda, J. Závada and J. Sicher
    Stereochemical studies. XLI. Solvolysis of cyclodecyl tosylates: Steric course of the reaction and conformational analysis
    1967, Vol. 32, Issue 6, pp. 2104–2121 [Abstract]
  • R. Řeřicha, P. Jarolímek and M. Horák
    Determination of the degree of branching in alkanes by infrared spectroscopy. II. Variation of the intensity of the antisymmetrical stretching vibration bands of C-H bonds in CH3 and CH2 groups
    1967, Vol. 32, Issue 5, pp. 1903–1912 [Abstract]
  • R. Řeřicha and M. Horák
    Determination of the degree of branching in alkanes by infrared spectroscopy. I. Resolution of overlapping absorption bands in the 3000-2900 cm-1 region
    1967, Vol. 32, Issue 3, pp. 1125–1136 [Abstract]
  • K. Waisser, A. Vystrčil and A. Vítek
    Triterpenes. XI. Infra-red absorption of triterpenic 1-hydroxy derivatives
    1966, Vol. 31, Issue 12, pp. 4741–4743 [Abstract]
  • K. Bláha, J. Smolíková and A. Vítek
    Amino acids and peptides. LXIV. Infrared spectra of substituted 2,5-piperazinediones and the detection of cis-peptide bonds in diastereomeric cyclohexapeptides
    1966, Vol. 31, Issue 11, pp. 4296–4311 [Abstract]
  • J. Závada, J. Krupička and J. Sicher
    Stereochemical studies. XXXIX. The effect of ring size on the rate of formation of cis- and trans-cycloalkanes from cycloalkyldimethylamine oxides
    1966, Vol. 31, Issue 11, pp. 4273–4285 [Abstract]
  • J. Krupička, J. Závada and J. Sicher
    Stereochemical studies. XXXV. The polarographic reduction of cycloalkyl bromides: E1/2 values and mechanism
    1965, Vol. 30, Issue 10, pp. 3570–3575 [Abstract]
  • J. Piťha and S. Vašíčková
    Stretching vibration of N-H bond in uracil, its derivatives and analogues
    1965, Vol. 30, Issue 6, pp. 1792–1798 [Abstract]
  • J. Závada and J. Sicher
    Stereochemical studies. XXXII. The preferred formation of cis-olefin in bimolecular 'onium salt eliminations
    1965, Vol. 30, Issue 2, pp. 438–444 [Abstract]
  • J. Sicher, M. Svoboda and J. Závada
    Stereochemical studies. XXXI. The metal-liquid ammonia reduction of alkyl-substituted cyclodecynes and cyclodeca-1,2-dienes: The mechanism of cycloalkyne reduction
    1965, Vol. 30, Issue 2, pp. 421–437 [Abstract]
  • M. Svoboda, J. Závada and J. Sicher
    Stereochemical studies. XXX. The anomalous course of metal-ammonia reduction of some cycloalkynes
    1965, Vol. 30, Issue 2, pp. 413–420 [Abstract]
  • M. Pánková and J. Sicher
    Stereochemical studies. XXIX. Steric effects in an intramolecular displacement reaction in open-chain systems
    1965, Vol. 30, Issue 2, pp. 388–412 [Abstract]
  • K. Kochloefl, P. Schneider, R. Řeřicha and V. Bažant
    Untersuchung über die Zusammensetzung der Braunkohlenteerfraktion vom Sdp. 220-280 °C II. Isoparaffinische und cycloparaffinische Kohlenwasserstoffe
    1963, Vol. 28, Issue 12, pp. 3362–3381 [Abstract]
  • J. Závada, J. Krupička and J. Sicher
    Stereochemical studies. XXVI. Determination of the stereochemistry of vicinal dibromides by polarographic reduction
    1963, Vol. 28, Issue 7, pp. 1664–1674 [Abstract]
  • J. Sicher, J. Závada and M. Svoboda
    Stereochemical studies. XXII. Bromine addition to medium ring cycloölefins: A transannular reaction
    1962, Vol. 27, Issue 8, pp. 1927–1938 [Abstract]
  • V. Horák and J. Závada
    Schwefelanaloga von Tropan-Derivaten II. Derivate der epimeren 8-Thia-bicyclo(1,2,3)octan-3-ole
    1962, Vol. 27, Issue 5, pp. 1224–1228 [Abstract]
  • J. Sicher, M. Tichý, F. Šipoš and M. Pánková
    Stereochemical studies. XX. Conformational studies on the 2-amino-4-t-butylcyclohexanols; An approach to quantitative conformational analysis of neighbouring group participation and solvolysis in 1,2-difunctional cyclohexane derivatives
    1961, Vol. 26, Issue 9, pp. 2418–2434 [Abstract]
  • R. Zahradník, R. Řeřicha, P. Axamit, M. Řežábková and S. Škramovský
    Über die Reaktion einiger Kationen von Schwermetallen mit wenig löslichen Calciumverbindungen
    1960, Vol. 25, Issue 1, pp. 146–158 [Abstract]
  • J. Sicher, M. Pánková, Jiří Jonáš and M. Svoboda
    Stereochemical studies. XVI. Stereospecific processes in open-chain 3-aminoalcohols. Synthesis of erythro- and threo-4-aminopentan-2-ol
    1959, Vol. 24, Issue 8, pp. 2727–2740 [Abstract]
  • M. Svoboda, J. Sicher, J. Farkaš and M. Pánková
    Stereochemical studies. IV. Reaction of Δ2-oxazolines with thioacetic acid. Syntheses of some diacyl-1,2-aminothiols
    1955, Vol. 20, Issue 6, pp. 1426–1438 [Abstract]
  • J. Sicher and M. Pánková
    Stereochemical studies. III. Steric course of the reaction of N-acyl derivatives of 1,2-aminoalcohols with thionyl chloride
    1955, Vol. 20, Issue 6, pp. 1409–1425 [Abstract]