Collect. Czech. Chem. Commun.
1979, 44, 533-541
https://doi.org/10.1135/cccc19790533
Application of the relaxation reagent Gd(FOD)3 (1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionate)gadolinium(III) in 1H NMR spectroscopy of adamantoid compounds
Jiří Karhana, Milan Hájekb, Zbyněk Ksandra and Luděk Vodičkab
a Department of Analytical Chemistry
b Laboratory of Synthetic Fuels, Prague Institute of Chemical Technology, 166 28 Prague 6
Abstract
This spin-lattice relaxation times T1 of protons in the presence of the shift reagent Eu(FOD)3-D27 and the relaxation reagent Gd(FOD)3 were employed for the structure analysis of 1-adamantanol, 4-diamantanol, adamantanone, and 2,2-dioxy-2-thiaadamantane. The structure models of the complex adducts of the substrates with Gd(FOD)3 are discussed. The dependence of the corrected spin-lattice relaxation rates on the relaxation reagent concentration is linear only in the region of low concentration.
