Collect. Czech. Chem. Commun.
1980, 45, 179-186
https://doi.org/10.1135/cccc19800179
Study of the nature of the complexes present in PdCl2 aqueous solution
Alexander Kaszonyi, Ján Vojtko and Mikuláš Hrušovský
Department of Organic Technology, Slovak Institute of Technology, 880 37 Bratislava
Abstract
The existence of complexes of palladium chlorides in aqueous solutions was examined for different chloride-to-palladium molar ratios. Spectral and potentiometric methods were employed in conjunction with the cryoscopic technique, and the complexes of palladium with chlorides were found to be only mononuclear ; the existence of binuclear complexes can be practically ruled out.