Collect. Czech. Chem. Commun.
1980, 45, 2965-2970
https://doi.org/10.1135/cccc19802965
Synthesis of bridgehead chloro-, bromo- and iodobicyclo[2.2.2]octanes
Jan Kopecký and Jaroslav Šmejkal
Institute of Hygiene and Epidemiology, Centre of Occupational Hygiene and Occupational Diseases, 100 42 Prague 10
Abstract
The paper describes transformations of hydroxy-, acetoxy- or methoxy-bridgehead bicyclo[2.2.2]octanes into bridgehead chloro, bromo or iodo derivatives by action of inorganic halides in the medium of orthophosphoric or polyphosphoric acids.