Collect. Czech. Chem. Commun.
1980, 45, 1780-1784
https://doi.org/10.1135/cccc19801780
O-O bond activation with cobalt(II)-ethylenediamine complexes in ion-exchange resins
Atanas Andreev, Lachezar Prahov and Dimitar Shopov
Institute of Organic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria
Abstract
The formation of Oxygen paramagnetic adducts of Co(II) containing ion-exchange resins in the presence of adsorbed ethylenediamine has been found. The EPR parameters of a complex of the type Co(III) (en)2O-2 and of O-2 species formed in the presence of Co(en)2+3 have been described. The catalytic properties of Co-ethylenediamine surface complexes with respect to the hydrogen peroxide decomposition reaction have been investigated and a probable mechanism has been suggested.
