Collect. Czech. Chem. Commun. 1981, 46, 3128-3133
https://doi.org/10.1135/cccc19813128

Reactions of carbonyl isothiocyanates with enamines of the type CH3-C(NH2)=CH-X

Michal Uher, Dušan Ilavský, Jozef Foltín and Katarína Škvareninová

Department of Organic Chemistry, Slovak Institute of Technology, 880 37 Bratislava

Abstract

Reactions of carbonyl isothiocyanates with enamines of the type CH3-C(NH2)=CH-X (X = CN, COOC2H5, or COCH3) were investigated. The formation of products of AdN, SN, and cyclization reactions is discussed on the basis of their IR, UV and mass spectra. In one case, the thermal cyclization was followed by differential thermal analysis.