Collect. Czech. Chem. Commun.
1981, 46, 535-541
https://doi.org/10.1135/cccc19810535
Relation of the temperature derivative of internal and cohesive energies of vaporization to the difference of heat capacities of liquids and gases
Václav Svoboda, Věra Uchytilová, Vladimír Majer and Jiří Pick
Department of Physical Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6
Abstract
Methods of Calculating the difference of heat capacities of liquids and gases at constant volume are discussed. The known methods of calculation are confronted with the method proposed in this work. It starts from the relations describing the mutual dependence of the temperature derivative of internal and cohesive energies of vaporization to the difference of the heat capacities of liquids and gases at constant volume.
