Collect. Czech. Chem. Commun.
1982, 47, 2890-2903
https://doi.org/10.1135/cccc19822890
Polarographic reduction of p-substituted 1-benzyl-3-carbamoylpyridinium chlorides
Josef Kuthan and Františka Pavlíková-Raclová
Department of Organic Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6
Abstract
Substituents effects (H, NO2, CN, COOCH3, CH3, CH3O, (CH3)2N, Cl, F) on polarographic characteristics of the title quaternary salts have been studied in water, anhydrous acetonitrile, and aqueous ethanol. In the last solvent a gradual disappearance of one of the polarographic waves takes place. Probable course of the investigated electrode processes and accompanying chemical transformations is discussed.
