Collect. Czech. Chem. Commun.
1984, 49, 2111-2115
https://doi.org/10.1135/cccc19842111
Synthesis of mono- and diacetylenic derivatives of silylferrocene
Abdel Ghani Ali El-Agameya and Levan P. Asatianib
a Faculty of Education, Damiatta, Mansoura University, Egypt
b Faculty of Chemistry, Tbilissi University, Tbilissi, USSR
Abstract
1-Ferrocenyl(methyl)phenylsilane (I) was prepared by silylation of ferrocene at low temperature. Mono- and diacetylenic compounds of silyferrocene were prepared by the interaction of chloroferrocenylsilane with mono- and dilithium acetylenic derivatives, respectively. It has been found that, catalytic hydrogenation of the prepared acetylenic compounds seem to be totally determined by steric considerations.
