Collect. Czech. Chem. Commun.
1985, 50, 697-703
https://doi.org/10.1135/cccc19850697
Liquid-liquid equilibrium. Applicability of the Redlich-Kister, NRTL and LEMF equations to heterogeneous systems
Josef P. Novák, Jaroslav Matouš and Jiří Pick
Department of Physical Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6
Abstract
The limits of applicability of the Redlich-Kister, NRTL and LEMF equations when applied to heterogeneous systems are specified. These limits follow from the requirement of solvability of relations of the equality of activities in coexisting phases on the one hand and of the monotonous dependence of activity coefficients on the other hand.
