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Collect. Czech. Chem. Commun. 1989, 54, 1036-1042
https://doi.org/10.1135/cccc19891036

Conversion of betulin into careyagenolide (2α,3β-dihydroxy-18α,19βH-ursan-28,20β-olide)

Jan Sejbala, Eva Klinotováa, Markéta Bludskáa, Jiří Klinota and Miloš Buděšínskýb

a Department of Organic Chemistry, Charles University, 128 40 Prague 2
b Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague 6

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  • Khusnutdinova El'mira F., Medvedeva Natalya I., Kazakov Dmitri V., Kukovinets Olga S., Lobov Alexander N., Suponitsky Kirill Yu., Kazakova Oxana B.: Stereospecific Oxidation of Diacetoxyheterobetulin with Ozone and Dimethyldioxirane. Natural Product Communications 2016, 11. <https://doi.org/10.1177/1934578X1601100407>
  • Shernyukov A. V., Salakhutdinov N. F., Tolstikov G. A.: Methods of the synthesis of A-seco derivatives of pentacyclic triterpenoids. Russ Chem Bull 2013, 62, 878. <https://doi.org/10.1007/s11172-013-0120-3>
  • Kazakova O. B., Khusnutdinova É. F., Medvedeva N. I., Lobov A. N., Suponitskii K. Yu.: Molecular structure of 1,2,6,6,10,16,17-heptamethyl-20-(acetoxymethyl)pentacyclo [12.8.0.02.11.05.10.015.20]docos-17-en-7-yl acetate. J Struct Chem 2012, 53, 954. <https://doi.org/10.1134/S0022476612050198>
  • Kvasnica Miroslav, Rudovska Iva, Cisarova Ivana, Sarek Jan: Reaction of lupane and oleanane triterpenoids with Lawesson's reagent. Tetrahedron 2008, 64, 3736. <https://doi.org/10.1016/j.tet.2008.02.023>
  • SEJBAL J., KLINOTOVA E., BLUDSKA M., KLINOT J., BUDESINSKY M.: ChemInform Abstract: Triterpenes. Part 90. Conversion of Betulin into Careyagenolide (2α,3β‐Dihydroxy‐18α,19βH‐ursan‐28,20β‐olide). ChemInform 1989, 20. <https://doi.org/10.1002/chin.198932281>