Collect. Czech. Chem. Commun.
1991, 56, 905-915
https://doi.org/10.1135/cccc19910905
Novel carrier molecules: lipophilic ammonium ylides for membrane transport of metal picrates
Vladimír Krála, Juraj Koudelkaa, Helena Mohylováb and David Šamana
a Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague 6
b Bateria, 274 01 Slaný
Abstract
The novel artificial carriers have been synthesized by introduction of lipophilic group of pyrrolidinomalonaldehyde and N-imidazolylmalonaldehyde.. These stable dipolar synthetic carriers were used for transport of metal picrates through a liquid membranes. The cation specificity of the transport was determined by the means of atomic absorption spectroscopy. Carrier properties of ylides were compared with N,N-dimethyldodecylamine N-oxide and DB18C6. The formation of complexes of ylides with some inorganic salts by the means of NMR spectroscopy, X-ray and potentiometric measurements of KS have been studied.
