Collect. Czech. Chem. Commun.
1993, 58, 748-753
https://doi.org/10.1135/cccc19930748
Vibrational Transition Probabilities and Dissociation Energy of the PF Molecule
Narayanan Rajamanickam, Manuel Fernandez Gomez and Juan Jesus Lopez Gonzalez
Department of Physical Chemistry, Faculty of Experimental Sciences, University of Granada, 23071 Jaen, Spain
Abstract
The Franck-Condon factors (vibrational transition probabilities) and r-centroids have been evaluated by a more reliable numerical interogation procedure for the bands of b1Σ+ - X3Σ- system of the PF molecule, using a suitable potential. The dissociation energy, De = 318 kJ mol-1 for the electronic ground state of this molecule has been estimated by fitting the electronegativity function to the experimental potential energy curve.
