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Collect. Czech. Chem. Commun. 1995, 60, 636-644
https://doi.org/10.1135/cccc19950636

Radical Additions to Fluoroolefins: Experimental Evidence for a Free-Radical Chain Mechanism in the Photo-Initiated Addition of Alcohols to Fluoroolefins

Oldřich Paletaa, Jaroslav Kvíčalaa, Zuzana Budkováa and Hans-Joachim Timpeb

a Department of Organic Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6, Czech Republic
b Polychrome GmbH, An der Bahn 80, 37520 Osterode, Germany

Crossref Cited-by Linking

  • Cı́rkva Vladimı́r, Böhm Stanislav, Paleta Oldřich: Radical addition reactions of fluorinated species. Part 8. Regioselectivity of radical additions to perfluoroalkylethylenes and quantum chemical calculations. Highly selective two-step synthesis of 4-(perfluoroalkyl)butane-1,2-diols. Journal of Fluorine Chemistry 2000, 102, 159. <https://doi.org/10.1016/S0022-1139(99)00237-7>
  • Cı́rkva Vladimı́r, Paleta Oldrich: Radical addition reactions of fluorinated species. Part 7. Highly selective two-step synthesis of 1-(polyfluoroalkyl)ethane-1,2-diols; regioselectivity of the additions of methylated 1,3-dioxolanes to perfluoroolefins. Journal of Fluorine Chemistry 1999, 94, 141. <https://doi.org/10.1016/S0022-1139(98)00356-X>
  • Cı́rkva Vladimı́r, Hájek Milan: Microwave photochemistry. Photoinitiated radical addition of tetrahydrofuran to perfluorohexylethene under microwave irradiation. Journal of Photochemistry and Photobiology A: Chemistry 1999, 123, 21. <https://doi.org/10.1016/S1010-6030(99)00049-0>
  • Paleta Oldřich, Církva Vladimír, Budková Zuzana, Böhm Stanislav: Radical addition reactions of fluorinated species Part 6. Regioselectivity of the addition of nucleophilic radicals to halogenopropenes and evidence for a steric effect of the chlorine substituent. Journal of Fluorine Chemistry 1997, 86, 155. <https://doi.org/10.1016/S0022-1139(97)00083-3>
  • Paleta Oldřich, Církva Vladimír, Kvicala Jaroslav: Radical additions to fluoro-olefins. photochemical mono-fluoroalkylation and sequential bis-fluoroalkylation of oxolane. Journal of Fluorine Chemistry 1996, 80, 125. <https://doi.org/10.1016/S0022-1139(96)03511-7>
  • Cîrkva Vladimír, Polák Radek, Paleta Oldřich: Radical additions to fluoroolefins. Photochemical fluoroalkylation of alkanols and alkane diols with perfluoro vinyl ethers; photo-supported O-alkylation of butane-1,4-diol with hexafluoropropene. Journal of Fluorine Chemistry 1996, 80, 135. <https://doi.org/10.1016/S0022-1139(96)03514-2>