Collect. Czech. Chem. Commun. 1995, 60, 636-644
https://doi.org/10.1135/cccc19950636

Radical Additions to Fluoroolefins: Experimental Evidence for a Free-Radical Chain Mechanism in the Photo-Initiated Addition of Alcohols to Fluoroolefins

Oldřich Paletaa, Jaroslav Kvíčalaa, Zuzana Budkováa and Hans-Joachim Timpeb

a Department of Organic Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6, Czech Republic
b Polychrome GmbH, An der Bahn 80, 37520 Osterode, Germany

Individual author index pages


Other CCCC articles of these authors

  • Pavel Herrmann, Jaroslav Kvíčala, Vladimír Pouzar and Hana Chodounská*
    Synthesis of Fluorinated Steroids Using a Novel Fluorinating Reagent Tetrabutylammonium Difluorodimethylphenylsilicate (TAMPS)
    2008, Vol. 73, Issue 12, pp. 1825–1834 [Abstract]
  • Ondřej Kysilka, Markéta Rybáčková, Martin Skalický, Magdalena Kvíčalová, Josef Cvačka and Jaroslav Kvíčala*
    HFPO Trimer-Based Alkyl Triflate, a Novel Building Block for Fluorous Chemistry. Preparation, Reactions and 19F gCOSY Analysis
    2008, Vol. 73, Issue 12, pp. 1799–1813 [Abstract]
  • Jaroslav Kvíčala*, Ondřej Baszczyňski, Alena Krupková and Denisa Stránská
    Hydroboration of 1,1'-Bi(cyclopent-1-ene) and 3,3'-Biindene: Experimental and Theoretical Study
    2006, Vol. 71, Issue 11-12, pp. 1611–1626 [Abstract]
  • Tomáš Bříza, Jaroslav Kvíčala* and Oldřich Paleta
    Synthesis of Polyfluorinated Alkynes, Novel Building Blocks for Fluorous Chemistry
    2003, Vol. 68, Issue 6, pp. 1039–1045 [Abstract]
  • Vladimír Církva, Robert Kaplánek, Oldřich Paleta* and Milan Kodíček
    Amphiphilic Perfluoroalkylated Derivatives of Aliphatic Triols: Hemocompatibility and Effect on Perfluorocarbon Emulsion
    2002, Vol. 67, Issue 10, pp. 1436–1448 [Abstract]
  • Jaroslav Kvíčala*, Tomáš Bříza, Oldřich Paleta and Jan Čermák
    Synthesis of (Polyfluoroalkyl)cyclopentenes as Model Compounds for Fluorophilic Cyclopentadienes
    2002, Vol. 67, Issue 9, pp. 1345–1358 [Abstract]
  • Karel Kefurt*, Jitka Moravcová, Šárka Bambasová, Kateřina Buchalová, Barbora Vymětalíková, Zdeňka Kefurtová, Jan Staněk and Oldřich Paleta
    Alkylation of Partially Protected Xylofuranoses and Tetritols with (2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl)oxirane and the Stability of Protecting Acetal Groups Towards Lewis Acid-Type Catalyst
    2001, Vol. 66, Issue 11, pp. 1665–1681 [Abstract]
  • Jaroslav Kvíčala* and Andrew Pelter
    (9H-Fluoren-9-ylidene)fluoromethyllithium, a Stabilized Fluoroalkenyl Carbanion. Preparation, Reactions, 13C and 19F NMR Spectra
    2001, Vol. 66, Issue 10, pp. 1508–1520 [Abstract]
  • Jan Čermák*, Kateřina Auerová, Huong Thi Thu Nguyen, Vratislav Blechta, Pavel Vojtíšek and Jaroslav Kvíčala
    Synthesis of Rhodium Complexes with Novel Perfluoroalkyl Substituted Cyclopentadienyl Ligands
    2001, Vol. 66, Issue 2, pp. 382–396 [Abstract]
  • Jaroslav Kvíčala*, Růžena Vlasáková, Jakub Plocar, Oldřich Paleta and Andrew Pelter
    Preparation of Intermediates for Fluorinated Lignans by Conjugated and Tandem Additions on 3-Fluorofuran-2(5H)-one
    2000, Vol. 65, Issue 5, pp. 772–788 [Abstract]
  • Lubor Fišera, Vladimír Ondruš and Hans-Joachim Timpe
    Derivatives of tetrahydro-2H-pyridine from photorearranged cycloadducts of nitrile oxides
    1990, Vol. 55, Issue 2, pp. 512–523 [Abstract]
  • Vladimír Oremus, Lubor Fišera, Hans-Joachim Timpe and Ute Lammel
    An unusually selective photo-induced rearrangement of 4-alkoxycarbonyl-5-formyl-2,3-dihydro-6H-1,3-oxazines. A new route to preparation of condensed lactones
    1988, Vol. 53, Issue 12, pp. 3171–3178 [Abstract]
  • Vladimír Oremus, Lubor Fišera and Hans-Joachim Timpe
    Preparation and photochemistry of 3-methoxycarbonyl substituted condensed isoxazolines
    1987, Vol. 52, Issue 12, pp. 2953–2960 [Abstract]
  • Lubor Fišera, Nadezhda D. Kozhina, Peter Oravec, Hans-Joachim Timpe, Ladislav Štibrányi and Larisa A. Badovskaya
    Photoinduced rearrangement of hydroxymethylisoxazolines, a route to enaminoaldehydes
    1986, Vol. 51, Issue 10, pp. 2167–2180 [Abstract]
  • Lubor Fišera, Vladimír Oremus, Hans-Joachim Timpe, Ladislav Štibrányi and Peter Zálupský
    An unusual effect of exo-endo configuration on the quantum yield Φ of photochemical rearrangement of 4-R-substituted 8-phenyl-3,5,10-trioxa-9-azabicyclo-[5,3,0]-8-decenes
    1986, Vol. 51, Issue 10, pp. 2158–2166 [Abstract]
  • Lubor Fišera, Vladimír Oremus, Ladislav Štibrányi, Hans-Joachim Timpe and Alena Máťušová
    Photo-induced rearrangement of isoxazolines - A pathway to 2,4,5,8-tetrahydro-1,3-dioxa-5-azocine derivatives
    1985, Vol. 50, Issue 9, pp. 1982–1993 [Abstract]
  • Lubor Fišera, Marta Konopíková, Ladislav Štibrányi and Hans-Joachim Timpe
    Solvent and substituent effects on rearrangement of 4-(4-X-phenyl)-2,7-dioxa-3-azabicyclo[3,3,0]oct-3-enes
    1985, Vol. 50, Issue 9, pp. 1971–1981 [Abstract]
  • Lubor Fišera, Samuel Ľaudár, Hans-Joachim Timpe, Peter Zálupský and Ladislav Štibrányi
    Preparation and photochemistry of furoisoxazolines. An extraordinarily unambiguous photo-induced rearrangement
    1984, Vol. 49, Issue 5, pp. 1193–1203 [Abstract]
  • Oldřich Paleta, Jaroslav Kvíčala and Václav Dědek
    Kinetics of acid-catalyzed hydrolysis of fluorinated propanoates
    1983, Vol. 48, Issue 10, pp. 2805–2811 [Abstract]
  • Oldřich Paleta, Rudolf Ježek and Václav Dědek
    Selective photochemical reduction of carbon-chlorine bond in fluoropropanoates and its quantum yields
    1983, Vol. 48, Issue 3, pp. 766–771 [Abstract]
  • Jiří Svoboda, Oldřich Paleta and Václav Dědek
    Synthetic transformations of dimethyl perfluoro-4-methyl-2-pentenedioate
    1982, Vol. 47, Issue 12, pp. 3418–3423 [Abstract]
  • Oldřich Paleta, Jiří Svoboda and Václav Dědek
    Anionic cis-trans isomerization of dialkyl perfluoro(4-methyl-2-pentene)dioates. A non-classical equilibrium dependence
    1982, Vol. 47, Issue 1, pp. 54–58 [Abstract]
  • Lubor Fišera, Anton Gáplovský, Hans-Joachim Timpe and Jaroslav Kováč
    Correlation of kinetic data of 1,3-dipolar cycloadditions of C-benzoyl-N-phenylnitrones with the homo energies of furan derivatives
    1981, Vol. 46, Issue 6, pp. 1504–1512 [Abstract]
  • Jiří Svoboda, Oldřich Paleta and Václav Dědek
    Derivatives of 2,3-difluoro-2-butenedioic acid and their isomerization reactions
    1981, Vol. 46, Issue 6, pp. 1495–1503 [Abstract]
  • Jiří Svoboda, Oldřich Paleta, František Liška and Václav Dědek
    Fluorinated 3-diethylaminopropenoates and their reactions
    1981, Vol. 46, Issue 6, pp. 1389–1396 [Abstract]
  • Jiří Svoboda, Oldřich Paleta and Václav Dědek
    Reaction of chlorodifluoropropenoates with potassium fluoride
    1981, Vol. 46, Issue 5, pp. 1272–1279 [Abstract]
  • Hans-Joachim Timpe, Reinhard Dietrich, Jürgen Böckelmann, Ingrid Friedel, Horst Bögel and Günther Haucke
    Mechanismus der Photo-Umlagerung von Benzylarylethern
    1981, Vol. 46, Issue 1, pp. 219–239 [Abstract]
  • Oldřich Paleta, Jiří Svoboda, Václav Havlů and Václav Dědek
    Anionic cis-trans isomerisation of dimethyl perfluoro-(4-methyl-2-pentene)dioate
    1980, Vol. 45, Issue 12, pp. 3360–3369 [Abstract]
  • Oldřich Paleta, Václav Havlů and Václav Dědek
    Ionic dimerisation of methyl trifluoropropenoate
    1980, Vol. 45, Issue 2, pp. 415–422 [Abstract]
  • Jiří Svoboda, Oldřich Paleta and Václav Dědek
    Ionic dimerisation of trifluoropropenenitrile and its addition reactions with methyl trifluoropropenoate
    1980, Vol. 45, Issue 2, pp. 406–414 [Abstract]
  • Oldřich Paleta, František Liška, Antonín Pošta and Václav Dědek
    Aluminium chloride induced isomerisation of 1,1,2-trichlorotrifluoroethane and 1,2-difluorotetrachloroethane
    1980, Vol. 45, Issue 1, pp. 104–114 [Abstract]
  • Oldřich Paleta, Jiří Svoboda and Václav Dědek
    UV-light induced cycloaddition of 3,4-dichloro-3,4,4-trifluoro-2-butanone to 2-methyl-2-butene
    1978, Vol. 43, Issue 11, pp. 2932–2941 [Abstract]