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Collect. Czech. Chem. Commun. 1997, 62, 1229-1238
https://doi.org/10.1135/cccc19971229

A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12

Bohumil Štíbra,b, Josef Holuba, Tomáš Jelíneka, Bohumír Grünera, Jiří Fuseka, Zbyněk Plzáka, Francesc Teixidorb, Clara Viñasb and John D. Kennedyc

a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež near Prague, Czech Republic
b Institute of Material Sciences, Campus de la UAB, 08913 Bellaterra, Spain
c School Of Chemistry, University of Leeds, Leeds LS2 9JT, England

Crossref Cited-by Linking

  • Bakardjiev Mario, Růžička Aleš, Růžičková Zdeňka, Tok Oleg L., Holub Josef, Hnyk Drahomír, Fanfrlík Jindřich, Štíbr Bohumil: Synthesis of closo-1,2-H2C2B8Me8 and 1,2-H2C2B8Me7X (X = I and OTf) Dicarbaboranes and Their Rearrangement Reactions. Inorg. Chem. 2019, 58, 2865. <https://doi.org/10.1021/acs.inorgchem.8b03550>
  • Štíbr Bohumil: Recent aspects of the ten-vertex dicarbaborane chemistry. Journal of Organometallic Chemistry 2018, 865, 4. <https://doi.org/10.1016/j.jorganchem.2018.01.010>
  • Bakardjiev Mario, Štíbr Bohumil, Tok Oleg L., Holub Josef: Unusual Closure of the Ten-Vertex Nido Cage via Alkylation: Regiospecific Synthesis of 3-Alkyl Derivatives of closo-1,2-C2B8H10. Inorg. Chem. 2018, 57, 1368. <https://doi.org/10.1021/acs.inorgchem.7b02783>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Lane Paul D., McKee Michael L., Wann Derek A., Hnyk Drahomír: Unusual Cage Rearrangements in 10-Vertex nido-5,6-Dicarbaborane Derivatives: An Interplay between Theory and Experiment. Inorg. Chem. 2017, 56, 852. <https://doi.org/10.1021/acs.inorgchem.6b02320>
  • Štíbr Bohumil: Ten-vertex dicarbaboranes from nido -5,6-C 2 B 8 H 12. Journal of Organometallic Chemistry 2015, 798, 30. <https://doi.org/10.1016/j.jorganchem.2015.04.005>
  • Bakardjiev Mario, Štíbr Bohumil, Holub Josef, Padělková Zdenka, Růžička Aleš: Simple Synthesis, Halogenation, and Rearrangement of closo-1,6-C2B8H10. Organometallics 2015, 34, 450. <https://doi.org/10.1021/om500988z>
  • Dolgushin Fedor M., Kostukovich Alexandr Yu, Pisareva Irina V., Konoplev Vitalii E., Chizhevsky Igor T.: Cluster rearrangement of isonido-ruthenacarboranes [1-(η6-1,4-Me2C6H4)-3(6)-Cl-isonido-1,2,4-RuC2B8H9] under thermal conditions. Journal of Organometallic Chemistry 2014, 751, 493. <https://doi.org/10.1016/j.jorganchem.2013.10.024>
  • Frank René, Auer Henry, Hey-Hawkins Evamarie: Functionalisation of the nido-dicarbaborate anion nido-7,8 by hydride abstraction. Journal of Organometallic Chemistry 2013, 747, 217. <https://doi.org/10.1016/j.jorganchem.2013.04.031>
  • Macías Ramón, Thornton-Pett Mark, Holub Josef, Spalding Trevor R., Faridoon Yousafzai, Štíbr Bohumil, Kennedy John D.: Polyhedral metallathiaborane chemistry: Synthesis and characterisation of metallathiaboranes based on the twelve-vertex icosahedral closo-{MSB10H10} unit, where M is Rh or Ir. Journal of Organometallic Chemistry 2008, 693, 435. <https://doi.org/10.1016/j.jorganchem.2007.11.014>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Hnyk Drahomír, Tok Oleg L., Milius Wolfgang, Wrackmeyer Bernd: Phosphacarborane Chemistry: The Synthesis of the Parent Phosphadicarbaboranesnido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]−, and Their 10-Cl Derivatives − Analogs of the Cyclopentadienide Anion. Eur J Inorg Chem 2002, 2002, 2320. <https://doi.org/10.1002/1099-0682(200209)2002:9<2320::AID-EJIC2320>3.0.CO;2-E>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Hnyk Drahomír, Tok Oleg L., Milius Wolfgang, Wrackmeyer Bernd: Phosphacarborane Chemistry: The Synthesis of the Parent Phosphadicarbaboranesnido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]−, and Their 10-Cl Derivatives − Analogs of the Cyclopentadienide Anion. Eur. J. Inorg. Chem. 2002, 2002, 2320. <https://doi.org/10.1002/1099-0682(200209)2002:9<2320::AID-EJIC2320>3.0.CO;2-E>
  • Holub Josef, Bakardjiev Mario, Štíbr Bohumil, Hnyk Drahomír, Tok Oleg L., Wrackmeyer Bernd: Two Isomeric Phosphacarboranes 2,1- and 6,1-PCB8H9, the First Representatives of the 10-Vertex closo Phosphacarborane Series. Inorg. Chem. 2002, 41, 2817. <https://doi.org/10.1021/ic020047g>
  • Bown Mark, Grüner Bohumı́r, Štı́br Bohumil, Fontaine Xavier L.R., Thornton-Pett Mark, Kennedy John D.: Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]. Journal of Organometallic Chemistry 2000, 614-615, 269. <https://doi.org/10.1016/S0022-328X(00)00615-X>
  • Holub Josef, Ormsby Daniel L, Kennedy John D, Greatrex Robert, Štı́br Bohumil: Phosphacarborane chemistry. New cluster isomers in the eleven-vertex nido-phosphadicarbaborane series: synthesis of the nido phosphadicarbaboranes 7,8,11-PC2B8H11, [7,8,11-PC2B8H10]− and 7-Ph-7,8,10-PC2B8H10. Inorganic Chemistry Communications 2000, 3, 178. <https://doi.org/10.1016/S1387-7003(00)00039-3>
  • Štı́br Bohumil, Holub Josef, Plešek Jaromı́r, Jelı́nek Tomáš, Grüner Bohumı́r, Teixidor Francesc, Viñas Clara: A simple route to essential tricarbollides. A high-yield synthesis of 7-amine-nido-7,8,9-tricarbaundecaboranes(10), 7-L-nido-7,8,9-C3B8H10 (where L=H3N, Me2NH, Me3N, and ButH2N). Journal of Organometallic Chemistry 1999, 582, 282. <https://doi.org/10.1016/S0022-328X(99)00068-6>
  • Janoušek Zbynek, Kaszynski Piotr: Heterodisubstituted 1,10-dicarba-closo-decaboranes from substituted nido-carborane precursors. Polyhedron 1999, 18, 3517. <https://doi.org/10.1016/S0277-5387(99)00300-9>
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