Collect. Czech. Chem. Commun. 1999, 64, 61-72
https://doi.org/10.1135/cccc19990061

Syntheses and Crystal Structures of Dichlorobis[tetramethyl(phenyl)cyclopentadienyl]titanium(IV) and Chlorobis[tetramethyl(phenyl)cyclopentadienyl]titanium(III)

Michal Horáčeka, Miroslav Polášeka, Volkmar Kupferb, Ulf Thewaltb and Karel Macha,*

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, 182 23 Prague 8, Czech Republic
b Sektion für Röntgen- und Elektronenbeugung, Universität Ulm, 89069 Ulm, Germany

Individual author index pages


Other CCCC articles of these authors

  • Jiří Pinkas, Róbert Gyepes, Ivana Císařová, Jiří Kubišta, Karel Mach and Michal Horáček*
    Dehydrocoupling of SiMe2H substituents in permethylated zirconocene complexes
    2011, Vol. 76, Issue 3, pp. 177–191 [Abstract]
  • Michal Horáček, Jan Merna, Róbert Gyepes, Jan Sýkora, Jiří Kubišta and Jiří Pinkas*
    Titanocene and ansa-titanocene complexes bearing 2,6-bis(isopropyl)phenoxide ligand(s). Syntheses, characterization and use in catalytic dehydrocoupling polymerization of phenylsilane
    2011, Vol. 76, Issue 1, pp. 75–94 [Abstract]
  • Vojtech Varga, Jiří Pinkas, Róbert Gyepes, Petr Štěpnička, Michal Horáček, Zdeněk Bastl and Karel Mach*
    Synthesis of zirconocene silsesquioxane complexes and their ethene polymerization activity in systems with methylaluminoxane
    2010, Vol. 75, Issue 1, pp. 105–119 [Abstract]
  • Vojtech Varga, Ivana Císařová, Michal Horáček, Jiří Pinkas, Jiří Kubišta and Karel Mach*
    Intramolecular alkoxide-tethered permethyltitanocene(III) complexes – synthesis and crystal structure
    2009, Vol. 74, Issue 3, pp. 453–468 [Abstract]
  • Vojtech Varga, Jiří Pinkas, Ivana Císařová, Róbert Gyepes, Karel Mach, Jiří Kubišta and Michal Horáček*
    Synthesis and Structure of Permethylcyclopentadienyltitanium Diisopropoxide Zwitterionic Complex
    2008, Vol. 73, Issue 8-9, pp. 1161–1176 [Abstract]
  • Jiří Pinkas, Róbert Gyepes, Ivana Císařová, Petr Štěpnička, Michal Horáček, Jiří Kubišta, Vojtech Varga and Karel Mach*
    Reactions of Doubly Tucked-In Permethyltitanocene with tert-Butanol and Propargyl Alcohol. The Crystal Structures of Unusual Hydrolytic Byproducts
    2008, Vol. 73, Issue 8-9, pp. 967–982 [Abstract]
  • Jaromír Hlavatý* and Miroslav Polášek
    Electrochemical Preparation of Alkynedial Tetramethyl Acetals
    2008, Vol. 73, Issue 1, pp. 19–23 [Abstract]
  • Michal Horáček*, Jiří Pinkas, Jiří Kubišta, Ivana Císařová, Róbert Gyepes and Petr Štěpnička
    Preparation and Crystal Structures of Low-Valent Zirconocene Complexes Containing Tetramethyl(phenyl)cyclopentadienyl Ligands
    2007, Vol. 72, Issue 5-6, pp. 679–696 [Abstract]
  • Lenka Lukešová, Róbert Gyepes, Vojtech Varga, Jiří Pinkas, Michal Horáček, Jiří Kubišta and Karel Mach*
    Synthesis and Crystal Structures of Dinuclear Trichloro(tetramethylcyclopentadienyl)titanium Complexes
    2006, Vol. 71, Issue 2, pp. 164–178 [Abstract]
  • Lenka Lukešová, Róbert Gyepes, Jiří Pinkas, Michal Horáček, Jiří Kubišta, Jiří Čejka and Karel Mach*
    Preparation and Crystal Structure of Bis(tert-butyltetramethylcyclopentadienyl)dichlorotitanium
    2005, Vol. 70, Issue 10, pp. 1589–1603 [Abstract]
  • Lenka Lukešová, Michal Horáček, Róbert Gyepes, Ivana Císařová, Petr Štěpnička, Jiří Kubišta and Karel Mach*
    Low-Valent Titanocene Products from Attempted Syntheses of Titanocene Bearing Dimethyl(3,3,3-trifluoropropyl)silyl Groups
    2005, Vol. 70, Issue 1, pp. 11–33 [Abstract]
  • Ivana Císařová, Vojtech Varga, Michal Horáček, Jiří Kubišta and Karel Mach*
    Exceptionally Symmetric Crystal Structure of (Pentabenzylcyclopentadienyl)(cyclooctatetraene)titanium(III)
    2004, Vol. 69, Issue 11, pp. 2036–2044 [Abstract]
  • Karel Mach*, Róbert Gyepes, Michal Horáček, Lidmila Petrusová and Jiří Kubišta
    Linear Dimerization of Terminal Alkynes by Bis(tetramethylphenylcyclopentadienyl)titanium-Magnesium Hydride and Acetylide Complexes
    2003, Vol. 68, Issue 10, pp. 1877–1896 [Abstract]
  • Oetze K. B. Staal, Dirk J. Beetstra, Andries P. Jekel, Bart Hessen*, Jan H. Teuben*, Petr Štěpnička, Róbert Gyepes, Michal Horáček, Jiří Pinkas and Karel Mach*
    Polymerization of Propene with Modified Constrained Geometry Complexes. Double-Bond Isomerization in Pendant Alkenyl Groups Attached to Cyclopentadienyl Ligands
    2003, Vol. 68, Issue 6, pp. 1119–1130 [Abstract]
  • Jaroslav Zemánek, Lenka Fröhlichová, Pavel Šindelář, Petr Štěpnička, Ivana Císařová, Vojtech Varga, Michal Horáček and Karel Mach*
    Synthesis of Trichloro(η5-alkenyltetramethylcyclopentadienyl)titanium(IV) Complexes and Their Activity in Styrene Polymerization
    2001, Vol. 66, Issue 9, pp. 1359–1374 [Abstract]
  • Jaroslav Zemánek, Petr Štěpnička, Karla Fejfarová, Róbert Gyepes, Ivana Císařová, Michal Horáček, Jiří Kubišta, Vojtech Varga and Karel Mach*
    Synthesis and Crystal Structures of Dimethylsilylene-Bridged (Amidocyclopentadienyl)dichlorotitanium(IV) Complexes with Various Substituents on the Cyclopentadienyl Ligand
    2001, Vol. 66, Issue 4, pp. 605–620 [Abstract]
  • Róbert Gyepes, Ivana Císařová, Michal Horáček, Jiří Čejka, Lidmila Petrusová and Karel Mach*
    Crystal Structures of Unusual Titanocene By-products from Attempted Dimerization of Terminal Alkynes
    2000, Vol. 65, Issue 8, pp. 1248–1261 [Abstract]
  • Volkmar Kupfer*, Karel Mach and Ulf Thewalt
    Synthesis and Structure of (π-Arene)titanium(II) Haloaluminate Complexes with Diarylmethane Ligands
    2000, Vol. 65, Issue 2, pp. 192–202 [Abstract]
  • Róbert Gyepes, Petr Štěpnička, Ulf Thewalt, Miroslav Polášek, Jiří Čejka, Michal Horáček and Karel Mach
    Synthesis and Crystal Structure of (Trimethylsilyl)acetylide-Bridged Dimeric Titanocene
    1998, Vol. 63, Issue 11, pp. 1884–1892 [Abstract]
  • Jiří Kroulík, Martin Chadim, Miroslav Polášek, Stanislav Nešpůrek and Josef Kuthan
    Synthesis of Some New Functionalized 2,4,4,6-Tetraphenyl-4H-thiopyrans and Study on Their Photocolouration
    1998, Vol. 63, Issue 5, pp. 662–680 [Abstract]
  • Günter Schmid, Ulf Thewalt, Petr Sedmera, Vladimír Hanuš and Karel Mach
    Dimeric Structures of Cp'TiCl2 Compounds with Bulky Substituents at the Cyclopentadienyl Rings
    1998, Vol. 63, Issue 5, pp. 636–645 [Abstract]
  • Petr Štěpnička, Ivana Císařová, Jan Sedláček, Jiří Vohlídal and Miroslav Polášek
    Synthesis of Triferrocenylbenzenes by Tantalum(V)-Catalyzed Cyclotrimerization of Ethynylferrocene. The Crystal Structure of 1,3,5-Triferrocenylbenzene
    1997, Vol. 62, Issue 10, pp. 1577–1584 [Abstract]
  • Jörg Hiller, Ulf Thewalt, Jaroslav Podlaha, Vladimír Hanuš and Karel Mach
    Synthesis and Crystal Structures of Dimeric Titanium(II) Bis(trimethylsilyl)acetylene Complexes [(C5H5-nMen)Ti(η2-Me3SiC≡CSiMe3)(μ-Cl)]2(n = 3-5)
    1997, Vol. 62, Issue 10, pp. 1551–1561 [Abstract]
  • Jörg Hiller, Vojtech Varga, Ulf Thewalt and Karel Mach
    Crystal Structures of Titanium(III) Bis(acetylide) Tweezer Complexes with Alkali Metal Cations
    1997, Vol. 62, Issue 9, pp. 1446–1456 [Abstract]
  • Susanne Müller and Ulf Thewalt
    Polynuclear Cadmium Compounds Containing cis-[Co(en)2(OH)2]+ Ligands
    1997, Vol. 62, Issue 2, pp. 257–264 [Abstract]
  • Jaroslav Podlaha, Petr Štěpnička, Róbert Gyepes, Vladimír Mareček, Alexander Lhotský, Miroslav Polášek, Jiří Kubišta and Martin Nejezchleba
    Hydrophobic Ferrocene Derivatives as Potential Standards in Electrochemistry
    1997, Vol. 62, Issue 2, pp. 185–198 [Abstract]
  • Jan-Willem F. Kaagman, Marco Rep, Michal Horáček, Petr Sedmera, Jiří Čejka, Vojtech Varga and Karel Mach
    Titanium-Catalyzed [4+2] and [6+2] Cycloadditions of 1,4-Bis(trimethylsilyl)buta-1,3-diyne
    1996, Vol. 61, Issue 12, pp. 1722–1728 [Abstract]
  • Michal Horáček, Róbert Gyepes, Ivana Císařová, Miroslav Polášek, Vojtech Varga and Karel Mach
    Syntheses and Crystal Structures of Bis[(trimethylsilyl)tetramethylcyclopentadienyl]titanium Dichloride and Monochloride
    1996, Vol. 61, Issue 9, pp. 1307–1320 [Abstract]
  • Karel Mach, Vojtech Varga, Günter Schmid, Jörg Hiller and Ulf Thewalt
    The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride
    1996, Vol. 61, Issue 9, pp. 1285–1294 [Abstract]
  • Karel Waisser, Jiří Kuneš, Jiří Klimeš, Miroslav Polášek and Želmíra Odlerová
    Relations between Structure and Antituberculotic Activity of 4-Alkoxybenzoic Acids
    1993, Vol. 58, Issue 1, pp. 191–196 [Abstract]
  • Miroslav Polášek, Karel Waisser and Tomáš Bouček
    Determination of the substituent constant σp- for the thioamide group -CSNH2 from the ionization of anilines and phenols
    1991, Vol. 56, Issue 12, pp. 2964–2968 [Abstract]
  • Jindřich Poláček, Helena Antropiusová, Lidmila Petrusová and Karel Mach
    Effect of triphenylphosphine on the cyclotrimerization of butadiene catalyzed by the TiCl4-EtAlCl2 system
    1990, Vol. 55, Issue 7, pp. 1756–1762 [Abstract]
  • Karel Mach, Helena Antropiusová, Vladimír Hanuš and Petr Sedmera
    Titanium-catalyzed Diels-Alder addition of bis(trimethylsilyl)acetylene to 1,3-cyclohexadiene
    1989, Vol. 54, Issue 11, pp. 3088–3091 [Abstract]
  • Jindřich Poláček, Lidmila Petrusová, Helena Antropiusová and Karel Mach
    The influence of alkali metal halides on the butadiene cyclotrimerization catalyzed by (benzene)titanium(II) complexes
    1989, Vol. 54, Issue 7, pp. 1839–1845 [Abstract]
  • Rolf Karlíček and Miroslav Polášek
    Binuclear complexes of aminoacetohydroxamic acid with copper(II) and iron(III)
    1987, Vol. 52, Issue 3, pp. 592–601 [Abstract]
  • Jindřich Poláček, Helena Antropiusová, Lidmila Petrusová and Karel Mach
    Deactivation of arenetitanium(II) bromoalane complexes in the cyclotrimerization of butadiene
    1986, Vol. 51, Issue 12, pp. 2751–2759 [Abstract]
  • Karel Mach, Jana Nováková, Vladimír Hanuš and Zdeněk Dolejšek
    Mass spectrometric and electron spin resonance study of allylic peroxyl radicals in the gas-phase reaction between allylic radicals and dioxygen
    1986, Vol. 51, Issue 12, pp. 2675–2684 [Abstract]
  • Jindřich Poláček, Karel Mach and Lidmila Petrusová
    Effect of mercury chlorides on the activity of complex titanium-based catalysts for the cyclotrimerization of butadiene
    1985, Vol. 50, Issue 9, pp. 2041–2047 [Abstract]
  • Karel Mach, Jana Nováková and Zdeněk Dolejšek
    Trapping of allylic radicals from the gas phase pyrolysis in the adamantane matrix - Isotropic ESR spectra at 77 K
    1984, Vol. 49, Issue 6, pp. 1325–1333 [Abstract]
  • Karel Mach, Lidmila Petrusová, Helena Antropiusová, Vladimír Hanuš, František Tureček and Petr Sedmera
    Intermolecular hydrogen transfer in unsaturated hydrocarbons induced by dimeric titanocene
    1983, Vol. 48, Issue 10, pp. 2924–2936 [Abstract]
  • Karel Mach and Karel Vacek
    Photolytic and thermal annealing of radical anions in gamma-irradiated ammonium salts of carboxylic acids
    1983, Vol. 48, Issue 1, pp. 203–214 [Abstract]
  • František Tureček, Vladimír Hanuš, Petr Sedmera, Helena Antropiusová and Karel Mach
    Cycloheptatriene dimers: New precursors of diamantane
    1981, Vol. 46, Issue 6, pp. 1474–1485 [Abstract]
  • Rolf Karlíček, Miroslav Polášek and Vladimír Jokl
    Ternary complexes of N-carboxymethylaminoacetohydroxamic acid
    1981, Vol. 46, Issue 5, pp. 1107–1115 [Abstract]
  • Karel Mach, Igor Janovský and Karel Vacek
    Photolytic and thermal annealing of radical anions gamma-irradiated monocarboxylic acids
    1979, Vol. 44, Issue 12, pp. 3632–3643 [Abstract]
  • Bohumír Matyska, Ludmila Petrusová, Karel Mach and Miroslav Švestka
    Cationic polymerization of isoprene: Initiation by complexes of titanium chloride with halogenoacetic acids
    1979, Vol. 44, Issue 4, pp. 1262–1272 [Abstract]
  • Rolf Karlíček, Miroslav Polášek and Vladimír Jokl
    N-Carboxymethylaminoaceto-N'-methylhydroxamic acid: Acid-base and chelating properties
    1978, Vol. 43, Issue 11, pp. 2897–2904 [Abstract]
  • Alexei D. Pershin, Imre Kende, Vlado Cholvad and Karel Mach
    Chemically induced dynamic nuclear polarization in the thermolysis of sulfides with azobisisobutyronitrile
    1978, Vol. 43, Issue 5, pp. 1349–1355 [Abstract]