Collect. Czech. Chem. Commun. 2002, 67, 1486-1492
https://doi.org/10.1135/cccc20021486

Synthesis and Chemistry of Highly Fluorinated Oxepane-2,7-diols

Pamela J. Lombardi, Yonghong Gan and David M. Lemal*

Department of Chemistry, Dartmouth College, Hanover, NH 03755, U.S.A.

References

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2. Rate of addition of the aqueous acid is probably the determining variable, rapid addition favoring the tetrol.
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4. Data collection and structure solution were conducted at the X-Ray Crystallographic Laboratory, 160 Kolthoff Hall, Department of Chemistry, University of Minnesota.
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5b. Hudlický M.: Reductions in Organic Chemistry, 2nd ed., p. 208. ACS Monograph 188; American Chemical Society, Washington, D. C. 1996.
6. Dehydration of tetrol to the dialdehyde with P4O10 has also been carried out with diphenyl ether as solvent1. In unpublished work cited in the monograph above, Hudlický similarly transformed dihemiacetal 6 into the dialdehyde.
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12. Spek A. L.: Acta Crystallogr., Sect. A: Fundam. Crystallogr. 1990, 46, C-34.