Collect. Czech. Chem. Commun. 2002, 67, 949-952
https://doi.org/10.1135/cccc20020949

New Multigram-Scale Preparation of 1,10-Dicarba-closo-decaborane

Josef Holub, Tomáš Jelínek and Zbyněk Janoušek*

Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68 Řež, Czech Republic

Individual author index pages


Other CCCC articles of these authors

  • Ivan Šnajdr, Zbyněk Janoušek and Martin Kotora
    Synthesis of novel C-(o-carboranyl)-2-deoxy-D-ribose conjugates
    Symposium Series 2011, Vol. 12, pp. 465–466 [Abstract]
    Published online 2015-08-20 10:24:38
  • Dmitry S. Perekalin, Evgeniya A. Trifonova, Ivan V. Glukhov, Josef Holub and Alexander R. Kudinov*
    Cyclopentadienyl ruthenium complexes with tricarbollide ligands
    2010, Vol. 75, Issue 11, pp. 1139–1148 [Abstract]
  • Drahomír Hnyk*, Josef Holub, Tomáš Jelínek, Jan Macháček and Michael G. S. Londesborough*
    Revisiting B20H16 by means of a joint computational/experimental NMR approach
    2010, Vol. 75, Issue 11, pp. 1115–1123 [Abstract]
  • Dmitry A. Loginov, Mikhail M. Vinogradov, Zoya A. Starikova, Pavel V. Petrovskii, Josef Holub and Alexander R. Kudinov*
    The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand
    2010, Vol. 75, Issue 9, pp. 981–993 [Abstract]
  • Radim Dostál*, Michael G. S. Londesborough*, Magdalena Kvíčalová, Jan Macháček, Ivana Císařová and Zbyněk Janoušek
    Incremental iodination of the eight-vertex closo monocarborane anion [closo-1-CB7H8]–: Preparation and characterization of [closo-1-CB7H5-6,7,8-I3]– and [closo-1-CB7H2-2,3,4,6,7,8-I6]–, and the synthesis of the first eight-vertex C-methylated carborane anion [1-CH3-closo-1-CB7H4-6,7,8-I3]–
    2010, Vol. 75, Issue 9, pp. 931–947 [Abstract]
  • Bryan Ringstrand*, Devon Bateman, Richard K. Shoemaker and Zbyněk Janoušek*
    Improved synthesis of [closo-1-CB9H10]– anion and new C-substituted derivatives
    2009, Vol. 74, Issue 3, pp. 419–431 [Abstract]
  • Josef Holub, Mario Bakardjiev and Bohumil Štíbr*
    Electrophilic Halogenation of nido-5,6-C2B8H12
    2006, Vol. 71, Issue 11-12, pp. 1549–1556 [Abstract]
  • Josef Holub, Mario Bakardjiev and Bohumil Štíbr*
    The Synthesis of 10-Halo-Substituted Derivatives of nido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]- and New Linear Correlations Between NMR Parameters
    2005, Vol. 70, Issue 11, pp. 1861–1872 [Abstract]
  • Tomáš Jelínek, Mark Thornton-Pett and John D. Kennedy*
    Monocarbaborane Anion Chemistry. Syntheses and Structures Within the closo Nine-Vertex System
    2002, Vol. 67, Issue 7, pp. 1035–1050 [Abstract]
  • Zbyněk Janoušek, Cameron L. Hilton, Peter J. Schreiber and Josef Michl*
    C-Halogenation of the closo-[CB11H12]- Anion
    2002, Vol. 67, Issue 7, pp. 1025–1034 [Abstract]
  • Drahomír Hnyk* and Josef Holub
    Two Forgotten Ten-Vertex arachno Triheteroboranes: arachno-5,6,9-C2SB7H11 and arachno-5,6,9-C3B7H13, Their Molecular Structure Determination by ab initio/NMR Approach and Synthesis of the Thiacarbaborane
    2002, Vol. 67, Issue 6, pp. 813–821 [Abstract]
  • Josef Holub, Mario Bakardjiev and Bohumil Štíbr*
    Some Halogenation Reactions of nido-7,8,9,11-P2C2B7H9
    2002, Vol. 67, Issue 6, pp. 783–790 [Abstract]
  • Zbyněk Janoušek*, Piotr Kaszynski, John D. Kennedy and Bohumil Štíbr
    NMR Assignments of [6-R-nido-5,6-C2B8H10]- Anions (where R = H, Me, and n-C6H13). An Irreversible 5 → 6 Alkyl Migration via a B9 Vertex-Swing Mechanism
    1999, Vol. 64, Issue 6, pp. 986–992 [Abstract]
  • Bohumil Štíbr*, Zbyněk Janoušek, Matthew Trammell, Bohumír Grüner and Zbyněk Plzák
    Oxidation of the [nido-6,9-C2B8H10]2- Anion - An Alternative Source of the 1,6- and 1,10-Dicarba-closo-decaboranes(10)
    1999, Vol. 64, Issue 6, pp. 971–976 [Abstract]
  • Bohumil Štíbr, Josef Holub, Tomáš Jelínek, Bohumír Grüner, Jiří Fusek, Zbyněk Plzák, Francesc Teixidor, Clara Viñas and John D. Kennedy
    A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
    1997, Vol. 62, Issue 8, pp. 1229–1238 [Abstract]
  • Jaromír Plešek, Bohumír Grüner and Josef Holub
    Synthesis and Properties of Cobaltacarboranes with Substituted Monoatomic Bridges Between Ligands of the 6,6'-μ-RnE(1,7-C2B9H10)2-2-Co Type
    1997, Vol. 62, Issue 6, pp. 884–893 [Abstract]
  • Bohumil Štíbr, Josef Holub, Francesc Teixidor and Clara Viñas
    The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]
    1995, Vol. 60, Issue 12, pp. 2023–2027 [Abstract]
  • Tomáš Jelínek, Bohumil Štíbr and John D. Kennedy
    Nine-Vertex Polyhedral Monoazaborane Chemistry: Synthesis and NMR Characterization of exo-6-Ligand-arachno-4-azanonaboranes(11), 6-L-4-NB8H11
    1994, Vol. 59, Issue 10, pp. 2244–2252 [Abstract]
  • Tomáš Jelínek, Josef Holub, Bohumil Štíbr, Xavier L. R. Fontaine and John D. Kennedy
    Nine- and Eight-Vertex Polyhedral Dicarbaborane Chemistry: New arachno and hypho Dicarbaboranes from arachno-4,5-C2B7H13: Isolation and Characterization of the [arachno-4,5-C2B7H12]- and [hypho-7,8-C2B6H13]- Anions, and of the Neutral Ligand Derivatives exo-6-(MeNC)-arachno-4,5-C2B7H11 and exo-5-L-hypho-4,9-C2B7H13 (L = NMe3 and NEt3)
    1994, Vol. 59, Issue 7, pp. 1584–1595 [Abstract]
  • Josef Holub, John D. Kennedy and Bohumil Štíbr
    Nine-Vertex Polyhedral Monothiaborane Chemistry. The First nido Thianonaborane: Isolation and Characterization by NMR of the [nido-9-SB8H9]- Anion, and its Conversion to Compounds of the 6-L-arachno-4-SB8H10 Series (where L = SMe2 and Pyridine)
    1994, Vol. 59, Issue 2, pp. 367–373 [Abstract]
  • John D. Kennedy, Bohumil Štíbr, Tomáš Jelínek, Xavier L. R. Fontaine and Mark Thornton-Pett
    Eleven-Vertex Polyhedral Dicarbaplatinaborane Chemistry. Aspects of the Chemistry of Some closo-Structured {1,2,3-PtC2B8} Species and Some Related Compounds
    1993, Vol. 58, Issue 9, pp. 2090–2120 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, František Mareš and Stanislav Heřmánek
    Unique Dialkylsulfonio-Methylation of the 7,8-C2B9H12(-) Ion to the 9-R2S-CH2-7,8-C2B9H11 Zwitterions by Formaldehyde and Dialkyl Sulfides. General Synthesis of the Compounds 10-R2E-7,8-C2B9H11 (E = O, S)
    1993, Vol. 58, Issue 7, pp. 1534–1547 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • František Adámek, Milan Hájek and Zbyněk Janoušek
    Relative Reactivities of 1,1,1-Trichloroethane and 1,1,1-Trichlorotrifluoroethane in Competitive Addition Reactions
    1992, Vol. 57, Issue 6, pp. 1291–1298 [Abstract]
  • Karl Nestor, Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett and Tomáš Jelínek
    Ten-Vertex Monocarbaborane Chemistry. A Convenient New Preparation of the [closo-1-CB9H10]- Anion and the Crystal and Molecular Structure of [(η5-C5Me5)2Ir2Cl3]+ [closo-1-CB9H10]-
    1992, Vol. 57, Issue 6, pp. 1262–1268 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Bohumil Štíbr, Karel Baše, Tomáš Jelínek, Xavier L. R. Fontaine, John D. Kennedy and Mark Thornton-Pett
    Polyhedral platinadicarbaborane chemistry. The molecular structure and some NMR properties of [9,9-(PPh3)2-arachno-9,5,6-PtC2B7H11]
    1991, Vol. 56, Issue 3, pp. 646–656 [Abstract]
  • Stanislav Heřmánek, Tomáš Jelínek, Jaromír Plešek, Bohumil Štíbr and Jiří Fusek
    Revision of nido-2,6-C2B7H11 to the arachno-4,5-C2B7H13 structure. Determination of the structure from NMR spectra and chemical origin
    1988, Vol. 53, Issue 11, pp. 2742–2752 [Abstract]
  • Bohumil Štíbr, Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek, Konstantin A. Solntsev and Nicolai T. Kuznetsov
    Symmetrical isomers of arachno-5,5'-X-(6,9-C2B8H13)2 (X = O and OSO2O) compounds
    1987, Vol. 52, Issue 4, pp. 957–959 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek
    Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives
    1987, Vol. 52, Issue 1, pp. 103–112 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Chemistry of compounds with the 1-carba-closo-dodecaborane(12) framework
    1986, Vol. 51, Issue 4, pp. 819–829 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Stanislav Heřmánek and Bohumil Štíbr
    Synthesis and reactions of 1,2-dicarba-closo-dodecarborane-1-yl tetrahydroborate(1-)
    1986, Vol. 51, Issue 1, pp. 81–89 [Abstract]
  • Tomáš Jelínek, Jaromír Plešek, Stanislav Heřmánek and Bohumil Štíbr
    Preparation of 7-substituted 7-carba-nido-undecaboranes(12)
    1985, Vol. 50, Issue 6, pp. 1376–1382 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Stanislav Heřmánek, Jaromír Plešek and Inessa A. Zakharova
    Synthesis and structure of μ-6,9-metalla-bis(ligand)-6,9-dicarba-nido-decarboranes(10) from the [6,9-C2B8H10]2- anion
    1984, Vol. 49, Issue 8, pp. 1891–1894 [Abstract]
  • Bohumil Štíbr, Zbyněk Janoušek, Karel Baše, Jaromír Plešek, Konstantin A. Solntsev, Lev A. Butman, Igor I. Kuznetsov and Nikolai T. Kuznetsov
    Synthesis of ten-vertex closo-metallacarbaboranes from 4-CB8H14
    1984, Vol. 49, Issue 7, pp. 1660–1664 [Abstract]
  • Jaromír Plešek, Tomáš Jelínek, Eva Drdáková, Stanislav Heřmánek and Bohumil Štíbr
    A convenient preparation of 1-CB11H12- and its C-amino derivatives
    1984, Vol. 49, Issue 7, pp. 1559–1562 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Bohumil Štíbr and Stanislav Heřmánek
    Synthesis and structure of iso-C4B18H22
    1983, Vol. 48, Issue 1, pp. 228–231 [Abstract]
  • Zbyněk Janoušek, Jaromír Plešek, Stanislav Heřmánek, Karel Baše, Lee J. Todd and W. F. Wright
    Synthesis and characteristics of sulfur interligand bridge-derivatives and of some S-substituted compounds in the (C2B9H11)2Co- series. Conformations of (C2B9H11)2Mx- metallocarboranes
    1981, Vol. 46, Issue 11, pp. 2818–2833 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Synthesis and properties of some icosahedral carborane B,B'-dithiols
    1980, Vol. 45, Issue 6, pp. 1775–1779 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Four new (CH3)2S·C2B9H11 isomers
    1978, Vol. 43, Issue 11, pp. 2862–2868 [Abstract]
  • Jaromír Plešek, Zbyněk Janoušek and Stanislav Heřmánek
    Chemistry of 9-mercapto-1,7-dicarba-closo-dodecaborane
    1978, Vol. 43, Issue 5, pp. 1332–1338 [Abstract]