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Collect. Czech. Chem. Commun. 2002, 67, 1035-1050
https://doi.org/10.1135/cccc20021035

Monocarbaborane Anion Chemistry. Syntheses and Structures Within the closo Nine-Vertex System

Tomáš Jelínek, Mark Thornton-Pett and John D. Kennedy*

The School of Chemistry of the University of Leeds, Leeds, LS2 9JT, U.K.

Crossref Cited-by Linking

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  • Štíbr Bohumil, Bakardjiev Mario, Holub Josef, Růžička Aleš, Padělková Zdeňka, Olejník Roman, Švec Petr: Skeletal Alkylcarbonation (SAC) Reactions as a Simple Design for Cluster–Carbon Insertion and Cross‐Coupling: High‐Yield Access to Substituted Tricarbollides from 6,9‐Dicarba‐arachno‐decaborane(14). Chemistry A European J 2011, 17, 13156. <https://doi.org/10.1002/chem.201102016>
  • Dostál Radim, Londesborough Michael G. S., Kvíčalová Magdalena, Macháček Jan, Císařová Ivana, Janoušek Zbyněk: Incremental iodination of the eight-vertex closo monocarborane anion [closo-1-CB7H8]–: Preparation and characterization of [closo-1-CB7H5-6,7,8-I3]– and [closo-1-CB7H2-2,3,4,6,7,8-I6]–, and the synthesis of the first eight-vertex C-methylated carborane anion [1-CH3-closo-1-CB7H4-6,7,8-I3]–. Collect. Czech. Chem. Commun. 2010, 75, 931. <https://doi.org/10.1135/cccc2010068>
  • Finze Maik: Synthesis and Characterization of 2‐Mono‐ and 1,2‐Diaminocarba‐closo‐dodecaborates M[1‐R‐2‐H2N‐closo‐CB11H10] (R=H, Ph, H2N, CyHN). Chemistry A European J 2009, 15, 947. <https://doi.org/10.1002/chem.200801497>
  • Franken Andreas, McGrath Thomas D., Stone F. Gordon A.: 10-Vertex Manganese−Dicarbollide Complexes from a Monocarbon Precursor. Synthesis and Cluster Vertex Functionalization of [1-OH-2,2,2-(CO)3-closo-2,1,10-MnC2B7H8]−. Organometallics 2009, 28, 225. <https://doi.org/10.1021/om800730n>
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  • Bakardjiev Mario, Holub Josef, Hnyk Drahomír, Štíbr Bohumil: Reductive Degradation of nido‐1‐CB8H12 into Smaller‐Cage Carborane Systems via New Monocarbaboranes [arachno‐5‐CB8H13]− and closo‐2‐CB6H8. Chemistry A European J 2008, 14, 6529. <https://doi.org/10.1002/chem.200800233>
  • Finze Maik: Carba-closo-dodecaborates with One or Two Alkynyl Substituents Bonded to Boron. Inorg. Chem. 2008, 47, 11857. <https://doi.org/10.1021/ic801610b>
  • Franken Andreas, McGrath Thomas D., Stone F. Gordon A.: A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies. Organometallics 2008, 27, 908. <https://doi.org/10.1021/om700865s>
  • Du Shaowu, Hodson Bruce E., Lei Peng, McGrath Thomas D., Stone F. Gordon A.: Penta- and Hexaruthenium Carbonyl ‘Raft' Complexes Supported by Monocarborane Cage Ligands. Inorg. Chem. 2007, 46, 6613. <https://doi.org/10.1021/ic700746j>
  • Štíbr Bohumil, Holub Josef, Bakardjiev Mario, Janoušek Zbyněk: Unusual interaction of alkynes with nine-vertex arachno-monocarbaboranes 4-CB8H14 and [4-CB8H13]−. Dalton Trans. 2007, 581. <https://doi.org/10.1039/B613237E>
  • Lei Peng, McGrath Thomas D., Stone F. Gordon A.: Oxidation of the Bis-molybdenum(0) Trianion [1,3,6-{Mo(CO)3}-3,6-(μ-H)2-1,1,1-(CO)3-2-Ph-closo-1,2-MoCB9H7]3-:  Metal and Boron Vertex Substitution and Cluster Expansion. Organometallics 2006, 25, 2011. <https://doi.org/10.1021/om0600543>
  • Lu Xiu Lian, McGrath Thomas D., Stone F. Gordon A.: Synthesis and Reactivity of 10- and 12-Vertex Cobalt−Monocarborane Anions Containing Multiple Metal Centers. Organometallics 2006, 25, 2590. <https://doi.org/10.1021/om060123d>
  • McGrath Thomas D., Du Shaowu, Hodson Bruce E., Lu Xiu Lian, Stone F. Gordon A.: Construction of Metal Butterflies on a Metallacarborane Scaffold. 1. Synthesis and Structures of Bimetallic Precursors. Organometallics 2006, 25, 4444. <https://doi.org/10.1021/om060417z>
  • McGrath Thomas D., Du Shaowu, Hodson Bruce E., Stone F. Gordon A.: Construction of Metal Butterflies on a Metallacarborane Scaffold. 2. Synthesis and Structures of Hetero-tri- and -tetrametallic Clusters. Organometallics 2006, 25, 4452. <https://doi.org/10.1021/om060418r>
  • Franken Andreas, Jelínek Tomáš, Taylor Richard G., Ormsby Daniel L., Kilner Colin A., Clegg William, Kennedy John D.: Polyhedral monocarbaborane chemistry. Some C-phenylated seven, eight, nine, ten, eleven and twelve-vertex species. Dalton Trans. 2006, 5753. <https://doi.org/10.1039/B609908D>
  • Du Shaowu, Jeffery John C., Kautz Jason A., Lu Xiu Lian, McGrath Thomas D., Miller Thomas A., Riis-Johannessen T., Stone F. Gordon A.: Reactions of the Dianion [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]2- with Transition-Metal Cations:  Facile Insertion and Then Extrusion of Cluster Vertexes. Inorg. Chem. 2005, 44, 2815. <https://doi.org/10.1021/ic048345w>
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  • Bullen Neil J., Kennedy John D.: Polyhedral Monocarbaborane Chemistry. Functionality and Isomerism: Reactions of the [6-Ph-nido-6-CB9H11]- Anion with Aminopyridines NC5H4NH2 to Yield Neutral arachno and closo Ten-Vertex Monocarbaborane Derivatives. Collect. Czech. Chem. Commun. 2005, 70, 1873. <https://doi.org/10.1135/cccc20051873>
  • Brellochs Bernd, Bačkovský Jaroslav, Štíbr Bohumil, Jelínek Tomáš, Holub Josef, Bakardjiev Mario, Hnyk Drahomír, Hofmann Mathias, Císarová Ivana, Wrackmeyer Berndt: New Ways to a Series of Parent Representatives of the Eight‐, Nine‐, and Ten‐Vertex Monocarbaborane Family. Eur J Inorg Chem 2004, 2004, 3605. <https://doi.org/10.1002/ejic.200400125>
  • Du Shaowu, Kautz Jason A., McGrath Thomas D., Stone F. Gordon A.: Synthesis and Structure of the Novel 11-Vertex Rhenacarborane Dianion [1,1,1-(CO)3-2-Ph-closo-1,2-ReCB9H9]2- and Its Reactivity toward Cationic Transition Metal Fragments. Organometallics 2003, 22, 2842. <https://doi.org/10.1021/om030122a>
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