Collect. Czech. Chem. Commun.
2003, 68, 1687-1709
https://doi.org/10.1135/cccc20031687
Synthesis, Spectroscopy and Spectroelectrochemistry of Chlorocarbonyl {1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene-κ2-N,N'}rhodium(I)
Taasje Mahabiersing, Henk Luyten, Ronald C. Nieuwendam and František Hartl*
Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands
Crossref Cited-by Linking
- Fomenko Iakov S., Romashev Nikolay F., Gushchin Artem L.: Advances in the chemistry of redox-active bis(imino)acenaphthenes (BIAN): A case of transition metal complexes. Coordination Chemistry Reviews 2024, 514, 215845. <https://doi.org/10.1016/j.ccr.2024.215845>
- Kass Dustin, Larson Virginia A., Corona Teresa, Kuhlmann Uwe, Hildebrandt Peter, Lohmiller Thomas, Bill Eckhard, Lehnert Nicolai, Ray Kallol: Trapping of a phenoxyl radical at a non-haem high-spin iron(II) centre. Nat. Chem. 2024, 16, 658. <https://doi.org/10.1038/s41557-023-01405-9>
- Bakaev I. V., Komlyagina V. I., Ulantikov A. A., Romashev N. F., Gushchin A. L.: Rhodium complexes bearing 2-(pyridin-2-yl)hydrazino acenaphthene-1-one: synthesis, structure and electrochemical studies. New J. Chem. 2024, 48, 18456. <https://doi.org/10.1039/D4NJ03595J>
- Louw Wynand J., Radhakrishnan Shankara G., Malan Frederick P., Bezuidenhout Daniela I.: Synthesis, electronic structure and interaction of rhodium(I) and iridium(I) bisimine-acenaphthalene complexes with CO2. Polyhedron 2023, 235, 116350. <https://doi.org/10.1016/j.poly.2023.116350>
- Komlyagina Veronika I., Romashev Nikolai F., Besprozvannykh Victoria K., Arakelyan Jemma, Wu Chengnan, Chubarov Alexey S., Bakaev Ivan V., Soh Yee Kiat, Abramov Pavel A., Cheung Kin Leung, Kompan’kov Nikolai B., Ryadun Aleksey A., Babak Maria V., Gushchin Artem L.: Effects of Bis(imino)acenaphthene (Bian)-Derived Ligands on the Cytotoxicity, DNA Interactions, and Redox Activity of Palladium(II) Bipyridine Complexes. Inorg. Chem. 2023, 62, 11541. <https://doi.org/10.1021/acs.inorgchem.3c01172>
- Romashev N. F., Mirzaeva I. V., Bakaev I. V., Komlyagina V. I., Komarov V. Yu., Fomenko I. S., Gushchin A. L.: STRUCTURE OF A BINUCLEAR RHODIUM(I) COMPLEX WITH THE ACENAPHTHENE- 1,2-DIIMINE LIGAND. J Struct Chem 2022, 63, 242. <https://doi.org/10.1134/S0022476622020056>
- Taylor James O., Culpeck Ryan, Chippindale Ann M., Calhorda Maria José, Hartl František: Effect of the 2-R-Allyl and Chloride Ligands on the Cathodic Paths of [Mo(η3-2-R-allyl)(α-diimine)(CO)2Cl] (R = H, CH3; α-diimine = 6,6′-Dimethyl-2,2′-bipyridine, Bis(p-tolylimino)acenaphthene). Organometallics 2021, 40, 1598. <https://doi.org/10.1021/acs.organomet.1c00038>
- Gushchin Artem L., Romashev Nikolai F., Shmakova Alexandra A., Abramov Pavel A., Ryzhikov Maxim R., Fomenko Iakov S., Sokolov Maxim N.: Novel redox active rhodium(iii) complex with bis(arylimino)acenaphthene ligand: synthesis, structure and electrochemical studies. Mendeleev Communications 2020, 30, 81. <https://doi.org/10.1016/j.mencom.2020.01.027>
- Ou Ya-Ping, Zhang Jing, Hu Yuxuan, Yin Jun, Chi Chunyan, Liu Sheng Hua: Oxidized divinyl oligoacene-bridged diruthenium complexes: bridged localized radical characters and reduced aromaticity in bridge cores. Dalton Trans. 2020, 49, 16877. <https://doi.org/10.1039/D0DT02883E>
- Ringenberg Mark R., Döttinger Florian: Anodic Mechanism of 1,1′‐Bis(diphenylphosphino)ferrocenedicarbonylnickel Determined by Low‐Temperature Spectroelectrochemistry. Eur J Inorg Chem 2019, 2019, 2430. <https://doi.org/10.1002/ejic.201900150>
- Romashev Nikolai F., Gushchin Artem L., Fomenko Iakov S., Abramov Pavel A., Mirzaeva Irina V., Kompan'kov Nikolay B., Kal'nyi Danila B., Sokolov Maxim N.: A new organometallic rhodium(I) complex with dpp-bian ligand: Synthesis, structure and redox behaviour. Polyhedron 2019, 173, 114110. <https://doi.org/10.1016/j.poly.2019.114110>
- Taylor James O., Veenstra Florentine L. P., Chippindale Ann M., Calhorda Maria José, Hartl František: Group 6 Metal Complexes as Electrocatalysts of CO2 Reduction: Strong Substituent Control of the Reduction Path of [Mo(η3-allyl)(CO)2(x,x′-dimethyl-2,2′-bipyridine)(NCS)] (x = 4–6). Organometallics 2019, 38, 1372. <https://doi.org/10.1021/acs.organomet.8b00676>
- Döttinger Florian, Ringenberg Mark R.: Reductive Carbonylation of [NiCl2(dippf)] (dippf = 1,1′-Bis(diisopropylphosphino)ferrocene) with Fe(CO)5 and (Spectro)electrochemistry of the Resulting [Ni(CO)2(dippf)]. Organometallics 2019, 38, 586. <https://doi.org/10.1021/acs.organomet.8b00881>
- Zhang Wei, Waddell Peter M., Tiedemann Margaret A., Padilla Christian E., Mei Jiajun, Chen Liye, Carrow Brad P.: Electron-Rich Metal Cations Enable Synthesis of High Molecular Weight, Linear Functional Polyethylenes. J. Am. Chem. Soc. 2018, 140, 8841. <https://doi.org/10.1021/jacs.8b04712>
- Ringenberg Mark R., Wittkamp Florian, Apfel Ulf-Peter, Kaim Wolfgang: Redox Induced Configurational Isomerization of Bisphosphine–Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes. Inorg. Chem. 2017, 56, 7501. <https://doi.org/10.1021/acs.inorgchem.7b00957>
- Schäfer K. Michael, Reinders Leonie, Fiedler Jan, Ringenberg Mark R.: Twisting and Tilting 1,1′-Bis(dialkylphosphino)ferrocene Bound to Low Valent Tricarbonylmaganese(I to −I). Inorg. Chem. 2017, 56, 14688. <https://doi.org/10.1021/acs.inorgchem.7b02627>
- Ou Ya-Ping, Zhang Jing, Zhang Fuxing, Kuang Daizhi, Hartl František, Rao Li, Liu Sheng Hua: Notable differences between oxidized diruthenium complexes bridged by four isomeric diethynyl benzodithiophene ligands. Dalton Trans. 2016, 45, 6503. <https://doi.org/10.1039/C6DT00109B>
- Grupp Anita, Bubrin Martina, Ehret Fabian, Zeng Qiang, Hartl František, Kvapilová Hana, Záliš Stanislav, Kaim Wolfgang: RuII(α‐diimine) or RuIII(α‐diimine·–)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal‐to‐Ligand Charge‐Transfer Excited‐State Configuration in the Ground State. Eur J Inorg Chem 2014, 2014, 110. <https://doi.org/10.1002/ejic.201301206>
- Tory Joanne, Gobaille-Shaw Gaël, Chippindale Ann M., Hartl František: Spectroelectrochemical study of complexes [Mo(CO)2(η3-allyl)(α-diimine)(NCS)] (α-diimine = bis(2,6-dimethylphenyl)-acenaphthenequinonediimine and 2,2′-bipyridine) exhibiting different molecular structure and redox reactivity. Journal of Organometallic Chemistry 2014, 760, 30. <https://doi.org/10.1016/j.jorganchem.2014.01.015>
- Tory Joanne, King Lisa, Maroulis Antonios, Haukka Matti, Calhorda Maria José, Hartl František: Solvent-Dependent Formation of Os(0) Complexes by Electrochemical Reduction of [Os(CO)(2,2′-bipyridine)(L)Cl2]; L = Cl–, PrCN. Inorg. Chem. 2014, 53, 1382. <https://doi.org/10.1021/ic402146t>
- Bubrin Martina, Schweinfurth David, Ehret Fabian, Záliš Stanislav, Kvapilová Hana, Fiedler Jan, Zeng Qiang, Hartl František, Kaim Wolfgang: Structure and Spectroelectrochemical Response of Arene–Ruthenium and Arene–Osmium Complexes with Potentially Hemilabile Noninnocent Ligands. Organometallics 2014, 33, 4973. <https://doi.org/10.1021/om5002815>
- Zeng Qiang, Messaoudani Mahdi, Vlček Antonín, Hartl František: Temperature-dependent reduction pathways of complexes fac-[Re(CO)3(N-R-imidazole)(1,10-phenanthroline)]+ (R=H, CH3). Electrochimica Acta 2013, 110, 702. <https://doi.org/10.1016/j.electacta.2013.02.018>
- Portius Peter, Davis Martin, Campbell Rory, Hartl František, Zeng Qiang, Meijer Anthony J. H. M., Towrie Michael: Dinitrogen Release from Arylpentazole: A Picosecond Time-Resolved Infrared, Spectroelectrochemical, and DFT Computational Study. J. Phys. Chem. A 2013, 117, 12759. <https://doi.org/10.1021/jp4077454>
- Zeng Qiang, Messaoudani Mahdi, Vlček Antonín, Hartl František: Electrochemical Reductive Deprotonation of an Imidazole Ligand in a Bipyridine Tricarbonyl Rhenium(I) Complex. Eur J Inorg Chem 2012, 2012, 471. <https://doi.org/10.1002/ejic.201101100>
- Schnöckelborg Eva-Maria, Khusniyarov Marat M., de Bruin Bas, Hartl František, Langer Thorsten, Eul Matthias, Schulz Stephen, Pöttgen Rainer, Wolf Robert: Unraveling the Electronic Structures of Low-Valent Naphthalene and Anthracene Iron Complexes: X-ray, Spectroscopic, and Density Functional Theory Studies. Inorg. Chem. 2012, 51, 6719. <https://doi.org/10.1021/ic300366m>
- Butsch Katharina, Klein Axel, Nitsche Sara, Stirnat Kathrin, Hawkett Jonathon R., McInnes Eric J. L., Bauer Matthias: Generation and characterisation of the phenoxyl-radical containing Cu(ii) complex [Cu(triaz)2]+ (triaz− = O,N chelating triazole-phenolate). Dalton Trans. 2012, 41, 11464. <https://doi.org/10.1039/c2dt31369c>
- Goor Layo, Duijnen Piet Th., Koper Carola, Jenneskens Leonardus W., Havenith Remco W. A., Hartl František: π-dimerization of pleiadiene radical cations at low temperatures revealed by UV–vis spectroelectrochemistry and quantum theory. J Solid State Electrochem 2011, 15, 2107. <https://doi.org/10.1007/s10008-011-1532-3>
- Miomandre Fabien, Allain Clémence, Clavier Gilles, Audibert Jean-Frédéric, Pansu Robert B., Audebert Pierre, Hartl František: Coupling thin layer electrochemistry with epifluorescence microscopy: An expedient way of investigating electrofluorochromism of organic dyes. Electrochemistry Communications 2011, 13, 574. <https://doi.org/10.1016/j.elecom.2011.03.013>
- Záliš Stanislav, Consani Cristina, Nahhas Amal El, Cannizzo Andrea, Chergui Majed, Hartl František, Vlček Antonín: Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2′-bipyridine and 1,10-phenanthroline complexes. Inorganica Chimica Acta 2011, 374, 578. <https://doi.org/10.1016/j.ica.2011.02.084>
- Uma Maheswari Palanisamy, Hartl František, Quesada Manuel, Buda Francesco, Lutz Martin, Spek Anthony L., Gamez Patrick, Reedijk Jan: Spectro-electrochemical and DFT studies of a planar Cu(II)–phenolate complex active in the aerobic oxidation of primary alcohols. Inorganica Chimica Acta 2011, 374, 406. <https://doi.org/10.1016/j.ica.2011.03.029>
- Tricas Hugo, Colon Marta, Ellis David, Macgregor Stuart A., McKay David, Rosair Georgina M., Welch Alan J., Glukhov Ivan V., Rossi Fulvio, Laschi Franco: Spectroscopic, structural, computational and (spectro)electrochemical studies of icosahedral carboranes bearing fluorinated aryl groups. Dalton Trans 2011, 40, 4200. <https://doi.org/10.1039/c0dt01798a>
- Klein Axel, Mering Yvonne von, Uthe André, Butsch Katharina, Schaniel Dominik, Mockus Nicholas, Woike Theo: Oxidation states and photoinduced metastable states in [Fe(CO)2(NO)2]. J Polyhedron 2010, 29, 2553. <https://doi.org/10.1016/j.poly.2010.05.028>
- Santi Saverio, Durante Christian, Donoli Alessandro, Bisello Annalisa, Orian Laura, Ganis Paolo, Ceccon Alberto, Benetollo Franco: Intervalence Charge Transfer in Cationic Heterotrinuclear Fe(III)−Rh(I)−Cr(0) Triads of the Polyaromatic Cyclopentadienyl−Indenyl Ligand. Organometallics 2010, 29, 2046. <https://doi.org/10.1021/om900903e>
- Hamacher Claudia, Hurkes Natascha, Kaiser André, Klein Axel, Schüren Andreas: Electrochemistry and Spectroscopy of Organometallic Terpyridine Nickel Complexes. Inorg. Chem. 2009, 48, 9947. <https://doi.org/10.1021/ic900753r>
- Hartl František, Renfrew Anna K., Lafolet Frédéric, Mahabiersing Taasje, Calhorda Maria José, Chardon-Noblat Sylvie, Haukka Matti, Deronzier Alain: Soluble Redox-Active Polymetallic Chains [{Ru0(CO)(L)(bpy)}m]n (bpy = 2,2′-bipyridine, L = PrCN, Cl−; m = 0, −1): Electrosynthesis and Characterization. Inorg. Chem. 2009, 48, 8233. <https://doi.org/10.1021/ic9008043>
- Santi Saverio, Durante Christian, Donoli Alessandro, Bisello Annalisa, Orian Laura, Ceccon Alberto, Crociani Laura, Benetollo Franco: Mixed Valence Properties in Ferrocenyl-Based Bimetallic FeCp−Indenyl−MLn Complexes: Effect of the MLn Group. Organometallics 2009, 28, 3319. <https://doi.org/10.1021/om800954b>
- Kaim Wolfgang, Fiedler Jan: Spectroelectrochemistry: the best of two worlds. Chem. Soc. Rev. 2009, 38, 3373. <https://doi.org/10.1039/b504286k>
- Busby Michael, Hartl František, Matousek Pavel, Towrie Mike, Vlček Antonín: Ultrafast Excited State Dynamics Controlling Photochemical Isomerization of N‐Methyl‐4‐[trans‐2‐(4‐pyridyl)ethenyl]pyridinium Coordinated to a {ReI(CO)3(2,2′‐bipyridine)} Chromophore. Chemistry A European J 2008, 14, 6912. <https://doi.org/10.1002/chem.200800188>
- Santi Saverio, Orian Laura, Donoli Alessandro, Durante Christian, Bisello Annalisa, Valentin Marilena Di, Ganis Paolo, Benetollo Franco, Ceccon Alberto: Tunable electronic coupling in iron–chromium mixed-valence ions of methylated Cp-indene ligands. J Organomet Chem 2008, 693, 3797. <https://doi.org/10.1016/j.jorganchem.2008.09.024>
- Singh Priti, Das Atanu Kumar, Sarkar Biprajit, Niemeyer Mark, Roncaroli Federico, Olabe José A., Fiedler Jan, Záliš Stanislav, Kaim Wolfgang: Redox Properties of Ruthenium Nitrosyl Porphyrin Complexes with Different Axial Ligation: Structural, Spectroelectrochemical (IR, UV−Visible, and EPR), and Theoretical Studies. Inorg. Chem. 2008, 47, 7106. <https://doi.org/10.1021/ic702371t>
- Singh Priti, Sieger Monika, Fiedler Jan, Su Cheng-Yong, Kaim Wolfgang: Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)X precursor compounds (X = Cl, NO2). Dalton Trans. 2008, 868. <https://doi.org/10.1039/B716307J>
- Santi Saverio, Orian Laura, Durante Christian, Bisello Annalisa, Benetollo Franco, Crociani Laura, Ganis Paolo, Ceccon Alberto: Tuning the Electronic Communication in Heterobimetallic Mixed‐Valence Ions of (1‐Ferrocenyl)‐ and (2‐Ferrocenyl)indenyl Rhodium Isomers. Chemistry A European J 2007, 13, 1955. <https://doi.org/10.1002/chem.200600724>
- Santi Saverio, Orian Laura, Durante Christian, Bencze Eva Zsuzsanna, Bisello Annalisa, Donoli Alessandro, Ceccon Alberto, Benetollo Franco, Crociani Laura: Metal–Metal Electronic Coupling in syn and anti Stereoisomers of Mixed‐Valent (FeCp)2‐, (RhL2)2‐, and (FeCp)(RhL2)‐as‐Indacenediide Ions. Chemistry A European J 2007, 13, 7933. <https://doi.org/10.1002/chem.200700052>
- Jin Baokang, Cheng Faliang, Liu Peng: A low temperature in situ infrared reflected absorbance spectroelectrochemical (LT IRRAS) cell. Journal of Electroanalytical Chemistry 2007, 603, 269. <https://doi.org/10.1016/j.jelechem.2007.02.012>
- Górski Marcin, Hartl František, Szymańska-Buzar Teresa: Isomeric Olefin Tetracarbonyl Complexes of Tungsten(I): An Infrared Spectroelectrochemical Study at Low Temperatures. Organometallics 2007, 26, 4066. <https://doi.org/10.1021/om700384g>
- Santi Saverio, Orian Laura, Donoli Alessandro, Durante Christian, Bisello Annalisa, Ganis Paolo, Ceccon Alberto, Crociani Laura, Benetollo Franco: Charge Transfer through Isomeric Unsaturated Hydrocarbons. Redox Switchable Optical Properties and Electronic Structure of Substituted Indenes with a Pendant Ferrocenyl. Organometallics 2007, 26, 5867. <https://doi.org/10.1021/om700673m>
- Fox Mark A., Nervi Carlo, Crivello Antonella, Low Paul J.: Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count. Chem. Commun. 2007, 2372. <https://doi.org/10.1039/b700110j>
- Cordiner Richard L., Smith Mark E., Batsanov Andrei S., Albesa-Jové David, Hartl František, Howard Judith A.K., Low Paul J.: The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands. Inorg Chim Ada 2006, 359, 946. <https://doi.org/10.1016/j.ica.2005.06.044>
- Singh Priti, Sarkar Biprajit, Sieger Monika, Niemeyer Mark, Fiedler Jan, Záliš Stanislav, Kaim Wolfgang: The Metal−NO Interaction in the Redox Systems [Cl5Os(NO)]n-, n = 1−3, and cis-[(bpy)2ClOs(NO)]2+/+: Calculations, Structural, Electrochemical, and Spectroscopic Results. Inorg. Chem. 2006, 45, 4602. <https://doi.org/10.1021/ic0517669>
- Hennig Horst, Schumer Frank, Reinhold Joachim, Kaden Heiner, Oelssner Wolfram, Schroth Werner, Spitzner Roland, Hartl František: Molecular Structures and Electronic Transitions of 3,6-Diphenyl-1,2-dithiin and Its Radical Cation: A Spectroelectrochemical and DFT Study. J. Phys. Chem. A 2006, 110, 2039. <https://doi.org/10.1021/jp0551059>
- Hartl František, Outersterp Josephina W. M. van: Multistep Electrochemical Reduction Path of Clusters [Os3(CO)10(α-diimine)]: Comparison of Electrochemical and Photochemical Os-Os(α-diimine) Bond Cleavage. Collect. Czech. Chem. Commun. 2006, 71, 237. <https://doi.org/10.1135/cccc20060237>
- Doux Marjolaine, Mézailles Nicolas, Ricard Louis, Le Floch Pascal, Vaz Pedro D., Calhorda Maria José, Mahabiersing Taasje, Hartl František: Syntheses, X-ray Structures, Photochemistry, Redox Properties, and DFT Calculations of Interconvertible fac- and mer-[Mn(SPS)(CO)3] Isomers Containing a Flexible SPS-Based Pincer Ligand. Inorg. Chem. 2005, 44, 9213. <https://doi.org/10.1021/ic050774m>
- Bruce Michael I., Low Paul J., Hartl František, Humphrey Paul A., de Montigny Frédéric, Jevric Martyn, Lapinte Claude, Perkins Gary J., Roberts Rachel L., Skelton Brian W., White Allan H.: Syntheses, Structures, Some Reactions, and Electrochemical Oxidation of Ferrocenylethynyl Complexes of Iron, Ruthenium, and Osmium. Organometallics 2005, 24, 5241. <https://doi.org/10.1021/om050483l>
- de Pater Boke C., Frühauf Hans‐Werner, Vrieze Kees, de Gelder René, Baerends Evert J., McCormack Drew, Lutz Martin, Spek Anthony L., Hartl František: Strongly Nucleophilic RhI Centre in Square‐Planar Complexes with Terdentate (κ3) 2,2′:6′,2′′‐Terpyridine Ligands: Crystallographic, Electrochemical and Density Functional Theoretical Studies. Eur J Inorg Chem 2004, 2004, 1675. <https://doi.org/10.1002/ejic.200300699>
- Hartl František, Mahabiersing Taasje, Chardon-Noblat Sylvie, Da Costa Philippe, Deronzier Alain: Redox-Active Polymers Based on Nonbridged Metal−Metal Bonds. Electrochemical Formation of [Os(bpy)(CO)(L)]n (bpy = 2,2‘-bipyridine; L = CO, MeCN) and of Their Reduced Forms: A Spectroelectrochemical Study. Inorg. Chem. 2004, 43, 7250. <https://doi.org/10.1021/ic049216i>
- Busby Michael, Matousek Pavel, Towrie Michael, Clark Ian P., Motevalli Majid, Hartl František, Vlček Antonín: Rhenium-to-Benzoylpyridine and Rhenium-to-Bipyridine MLCT Excited States of fac-[Re(Cl)(4-benzoylpyridine)2(CO)3] and fac-[Re(4-benzoylpyridine)(CO)3(bpy)]+: A Time-Resolved Spectroscopic and Spectroelectrochemical Study. Inorg. Chem. 2004, 43, 4523. <https://doi.org/10.1021/ic049659m>
- Sieger Monika, Sarkar Biprajit, Záliš Stanislav, Fiedler Jan, Escola Natalia, Doctorovich Fabio, Olabe José A., Kaim Wolfgang: Establishing the NO oxidation state in complexes [Cl5(NO)M]n−, M = Ru or Ir, through experiments and DFT calculations. Dalton Trans. 2004, 1797. <https://doi.org/10.1039/B404121F>