Collect. Czech. Chem. Commun. 2004, 69, 2036-2044
https://doi.org/10.1135/cccc20042036

Exceptionally Symmetric Crystal Structure of (Pentabenzylcyclopentadienyl)(cyclooctatetraene)titanium(III)

Ivana Císařováa, Vojtech Vargab, Michal Horáčekc, Jiří Kubištac and Karel Machc,*

a Department of Inorganic Chemistry, Charles University, Faculty of Science, Hlavova 2030, 128 40 Prague 2, Czech Republic
b Research Institute of Inorganic Chemistry, 400 01 Ústí nad Labem, Czech Republic
c J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23 Prague 8, Czech Republic

References

1. Okuda J.: Top. Curr. Chem. 1992, 160, 97. <https://doi.org/10.1007/3-540-54324-4_3>
2. Janiak C., Schumann H.: Adv. Organomet. Chem. 1991, 33, 291. <https://doi.org/10.1016/S0065-3055(08)60698-X>
3. Schmid G., Thewalt U., Troyanov S. I., Mach K.: J. Organomet. Chem. 1993, 453, 185. <https://doi.org/10.1016/0022-328X(93)83109-9>
4. Delville-Desbois M.-H., Mross S., Astruc D., Linares J., Varret F., Rabaa H., Le Beuze A., Saillard J.-Y., Culp R. D., Atwood D. A., Cowley A. H.: J. Am. Chem. Soc. 1996, 118, 4133. <https://doi.org/10.1021/ja953603x>
5a. Martins A. M., Branquinho R., Cui J., Dias A. R., Duarte M. T., Fernandes J., Rodrigues S. S.: J. Organomet. Chem. 2004, 689, 2368. <https://doi.org/10.1016/j.jorganchem.2004.04.027>
5b. Song L.-C., Zhang L.-Y., Hu Q.-M., Huang X.-Y.: Inorg. Chim. Acta 1995, 230, 127. <https://doi.org/10.1016/0020-1693(94)04316-N>
6. Schmid G., Thewalt U., Polášek M., Mach K., Sedmera P.: J. Organomet. Chem. 1994, 482, 231. <https://doi.org/10.1016/0022-328X(94)88206-1>
7. Schmid G., Thewalt U., Sedmera P., Hanuš V., Mach K.: Collect. Czech. Chem. Commun. 1998, 63, 636. <https://doi.org/10.1135/cccc19980636>
8. For Co, Rh, see: Chambers J. W., Baskar A. J., Bott S. G., Atwood J. L., Rausch M. D.: Organometallics 1986, 5, 1635. <https://doi.org/10.1021/om00139a020>
9. Rausch M. D., Tsai W.-M., Chambers J.-W., Rogers R. D., Alt H. G.: Organometallics 1989, 8, 816. <https://doi.org/10.1021/om00105a038>
10. For Fe, Lu, see: Schumann H., Janiak C., Köhn R. D., Loebel J., Dietrich A.: J. Organomet. Chem. 1989, 365, 137. <https://doi.org/10.1016/0022-328X(89)87174-8>
11. Zanello P., Cinquantini A., Mangani S., Opromolla G., Pardi L., Janiak C., Rausch M. D.: J. Organomet. Chem. 1994, 471, 171. <https://doi.org/10.1016/0022-328X(94)88122-7>
12a. Hitchcock P. B., Kerton F. M., Lawless G. A.: J. Am. Chem. Soc. 1998, 120, 10264. <https://doi.org/10.1021/ja981934e>
12b. Horáček M., Kupfer V., Thewalt U., Štěpnička P., Polášek M., Mach K.: Organometallics 1999, 18, 3572. <https://doi.org/10.1021/om990286k>
12c. Lukešová L., Horáček M., Štěpnička P., Fejfarová K., Gyepes R., Císařová I., Kubišta J., Mach K.: J. Organomet. Chem. 2002, 659, 186.
13a. Bercaw J. E., Brintzinger H. H.: J. Am. Chem. Soc. 1971, 93, 2046.
13b. Bercaw J. E., Marvich R. H., Bell L. G., Brintzinger H. H.: J. Am. Chem. Soc. 1972, 94, 1219. <https://doi.org/10.1021/ja00759a032>
13c. Bercaw J. E.: J. Am. Chem. Soc. 1974, 96, 5087. <https://doi.org/10.1021/ja00823a012>
14. Kupfer V., Thewalt U., Tišlerová I., Štěpnička P., Gyepes R., Kubišta J., Horáček M., Mach K.: J. Organomet. Chem. 2001, 620, 39. <https://doi.org/10.1016/S0022-328X(00)00784-1>
15. Sandwich metal complexes with two aromatic ligands, e.g., M(cot)2 are also named metallocenes. Seyferth D.: Organometallics 2004, 23, 3562. <https://doi.org/10.1021/om0400705>
16a. van der Wal H. R., Overzet F., van Oven H. O., de Boer J. L., de Liefde Meijer H. J., Jellinek F.: J. Organomet. Chem. 1975, 92, 329. <https://doi.org/10.1016/S0022-328X(00)85684-3>
16b. Horáček M., Hiller J., Thewalt U., Štěpnička P., Mach K.: J. Organomet. Chem. 1998, 571, 77. <https://doi.org/10.1016/S0022-328X(98)00870-5>
17. Dohmeier C., Baum E., Ecker A., Koppe R., Schnöckel H.: Organometallics 1996, 15, 4702. <https://doi.org/10.1021/om960375m>
18a. Demerseman B., Bouquet G., Bigorgne M.: J. Organomet. Chem. 1975, 101, C24. <https://doi.org/10.1016/S0022-328X(00)86409-8>
18b. Blenkers J., Bruin P., Teuben J. H.: J. Organomet. Chem. 1985, 297, 61. <https://doi.org/10.1016/0022-328X(85)80397-1>
19. Kool L. B., Rausch M. D., Rogers R. D.: J. Organomet. Chem. 1985, 297, 289. <https://doi.org/10.1016/0022-328X(85)80430-7>
20a. Samuel E., Labauze G., Vivien D.: J. Chem. Soc., Dalton Trans. 1979, 956. <https://doi.org/10.1039/dt9790000956>
20b. Samuel E., Labauze G., Vivien D.: J. Chem. Soc., Dalton Trans. 1981, 2353. <https://doi.org/10.1039/dt9810002353>
21. Kroon P. A., Helmholdt R. B.: J. Organomet. Chem. 1970, 25, 451. <https://doi.org/10.1016/S0022-328X(00)87847-X>
22. Antropiusová H., Dosedlová A., Hanuš V., Mach K.: Transition Met. Chem. (London) 1981, 6, 90. <https://doi.org/10.1007/BF00626113>
23. Hirsch S. S., Bailey W. J.: J. Org. Chem. 1978, 43, 4090. <https://doi.org/10.1021/jo00415a022>
24a. Otwinowski Z., Minor W.: HKL Denzo and Scalepack Program Package. Nonius BV, Delft 1997.
24b. For a reference, see: Otwinowski Z., Minor W.: Methods Enzymol. 1997, 276, 307. <https://doi.org/10.1016/S0076-6879(97)76066-X>
25. Altomare A., Burla M. C., Camalli M., Cascarano G., Giacovazzo C., Guagliardi A., Polidori G.: J. Appl. Crystallogr. 1994, 27, 435.
26. Sheldrick G. M.: SHELXL97, Program for Crystal Structure Refinement from Diffraction Data. University of Göttingen, Göttingen 1997.