New Alkali Metal and Tetramethylammonium Tetrafluoroarsenates(III), Their Vibrational Spectra and Crystal Structure of Cesium Tetrafluoroarsenate(III)

Klampfer, Peter; Benkič, Primož; Lesar, Antonija; Volavšek, Bogdan; Ponikvar, Maja; Jesih, Adolf

doi:10.1135/cccc20040339

CCCC > Archive > 2004, Volume 69 > Issue 2 > p. 339

New Alkali Metal and Tetramethylammonium Tetrafluoroarsenates(III), Their Vibrational Spectra and Crystal Structure of Cesium Tetrafluoroarsenate(III)

Peter Klampfer^a, Primož Benkič^a, Antonija Lesar^a, Bogdan Volavšek^b, Maja Ponikvar^a and Adolf Jesih^a,*

^a Institute Jožef Stefan, Jamova 39, 1000 Ljubljana, Slovenia
^b Faculty of Chemistry and Chemical Engineering, Smetanova 17, 2000 Maribor, Slovenia

Abstract

The title compounds were synthesised by the reaction of alkali metal and tetramethylammonium fluorides with liquid AsF₃. Crystal structure of CsAsF₄ was determined. Raman and infrared spectra of the title compounds were analysed.

Keywords: Fluoroarsenates(III); Arsenates; Arsene fluoride; Crystal structure; Infrared spectroscopy; Raman spectroscopy; X-Ray diffraction.

References: 36 live references.

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New Alkali Metal and Tetramethylammonium Tetrafluoroarsenates(III), Their Vibrational Spectra and Crystal Structure of Cesium Tetrafluoroarsenate(III)

Abstract