Collect. Czech. Chem. Commun. 2005, 70, 1873-1890
https://doi.org/10.1135/cccc20051873

Polyhedral Monocarbaborane Chemistry. Functionality and Isomerism: Reactions of the [6-Ph-nido-6-CB9H11]- Anion with Aminopyridines NC5H4NH2 to Yield Neutral arachno and closo Ten-Vertex Monocarbaborane Derivatives

Neil J. Bullen and John D. Kennedy*

The School of Chemistry of the University of Leeds, Leeds, UK LS2 9JT, England, U.K.

Individual author index pages


Other CCCC articles of these authors

  • Ramón Macías*, John D. Kennedy, Jonathan Bould and Mark Thornton-Pett
    Synthesis and characterization of dicarboranylmethylammonium polyoxometallates
    2010, Vol. 75, Issue 11, pp. 1075–1096 [Abstract]
  • Michael J. Carr, William Clegg, John D. Kennedy*, Michael G. S. Londesborough and Colin A. Kilner
    Macropolyhedral boron-containing cluster chemistry [S2B16H17]–. A new eighteen-vertex thiaborane anion
    2010, Vol. 75, Issue 8, pp. 807–812 [Abstract]
  • Michael G. S. Londesborough, Colin A. Kilner and John D. Kennedy*
    Macropolyhedral Boron-Containing Cluster Chemistry. Intermolecular Coordination via Hydrogen-Metal Interaction. The Solvent-Free Synthesis and Dimeric Constitution of [Pd2B36H40(PMe2Ph)4]
    2007, Vol. 72, Issue 12, pp. 1639–1645 [Abstract]
  • Jonathan Bould, Simon J. Teat and John D. Kennedy*
    Polyhedral Dipalladaborane Chemistry. The Molecular Structure and Cluster Electron Count of [7,8-(PPh3)2-7,8-(μ-PPh2)-9,11-(OEt)2-nido-7,8-Pd2B9H8]
    2007, Vol. 72, Issue 12, pp. 1631–1638 [Abstract]
  • Michael J. Carr, Michael G. S. Londesborough, Jonathan Bould, Ivana Císařová, Bohumil Štíbr and John D. Kennedy*
    Macropolyhedral Boron-Containing Cluster Chemistry. A Metallathiaborane from S2B17H17: Isolation and Characterisation of [(PMe2Ph)2PtS2B16H16]; A neo-arachno Ten-Vertex Cluster Shape, and the Constitution of the [arachno-B10H15]- Anion
    2005, Vol. 70, Issue 4, pp. 430–440 [Abstract]
  • Jonathan Bould, Mark Bown and John D. Kennedy*
    Polyhedral Oxaruthenaborane Chemistry. Characterisation of a [(η6-C6Me6)RuOB9H13] Species of arachno Eleven-Vertex Cluster Character and Other Aspects of Oxaborane Chemistry
    2005, Vol. 70, Issue 4, pp. 410–429 [Abstract]
  • Tomáš Jelínek, Mark Thornton-Pett and John D. Kennedy*
    Monocarbaborane Anion Chemistry. Syntheses and Structures Within the closo Nine-Vertex System
    2002, Vol. 67, Issue 7, pp. 1035–1050 [Abstract]
  • Andreas Franken, Colin A. Kilner, Mark Thornton-Pett and John D. Kennedy*
    Polyhedral Monocarbaborane Chemistry. A Review of Recent Developments Among C-Aryl Monocarbaborane Systems
    2002, Vol. 67, Issue 7, pp. 869–912 [Abstract]
  • Zbyněk Janoušek*, Piotr Kaszynski, John D. Kennedy and Bohumil Štíbr
    NMR Assignments of [6-R-nido-5,6-C2B8H10]- Anions (where R = H, Me, and n-C6H13). An Irreversible 5 → 6 Alkyl Migration via a B9 Vertex-Swing Mechanism
    1999, Vol. 64, Issue 6, pp. 986–992 [Abstract]
  • Udo Dörfler, Paul A. Salter, Xavier L. R. Fontaine, Norman N. Greenwood, John D. Kennedy* and Mark Thornton-Pett
    Polyhedral Azaplatinaborane Chemistry. Reaction of Members of the hypho-Type Family R'H2NB8H11NHR with [PtCl2(PMe2Ph)2] and [PtCl2(PPh3)2]. Formation of Members of the Family of Open Seven-Boron Species [3,3-(PMe2Ph)2-3-PtB7H10-μ-5,6-(NHR)]
    1999, Vol. 64, Issue 6, pp. 947–958 [Abstract]
  • Young-hee Kim, Yvonne M. McKinnes, Paul A. Cooke, Robert Greatrex, John D. Kennedy* and Mark Thornton-Pett
    Metallaborane Reaction Chemistry. Part 7. B-Frame Supported Bimetallics: Ligand-to-β-Metal Organometallic Interaction in Dimetallaboranes and an Interesting Ligand Displacement Cascade
    1999, Vol. 64, Issue 6, pp. 938–946 [Abstract]
  • Hai-Jun Yao, Chun-Hua hu, Jie Sun, Ruo-Shui Jin, Pei-Ju Zheng, Jonathan Bould, Robert Greatrex, John D. Kennedy*, Daniel L. Ormsby and Mark Thornton-Pett
    Isolation and Structure of [(PPh3)3(PPh2)2Pd4B20H16]. A Possible Prognostic for New Globular Borane-Based Cluster Architectures
    1999, Vol. 64, Issue 6, pp. 927–937 [Abstract]
  • Young-hee Kim, Robert Greatrex and John D. Kennedy
    Metallaborane Reaction Chemistry. Part 4. Polyhedral Thiametallaborane Synthesis via Direct Incorporation of Sulfur Into Metallaboranes
    1997, Vol. 62, Issue 8, pp. 1289–1298 [Abstract]
  • Jonathan Bould, Paul Brint, John D. Kennedy, Mark Thornton-Pett, Lawrence Barton and Nigam P. Rath
    Metallaborane Reaction Chemistry. Part 3. Reaction of Carbon Monoxide with [6-H-6-(PPh3)-6P,5C-μ-(2-Ph2PC6H4)-nido-6-IrB9H12] and the Isolation and Characterisation of Two arachno-6-Monoiridadecaboranes [6-(CO)-6-H-6,9-(PPh3)2-6P,5C-μ-(2-Ph2PC6H4)-arachno-6-IrB9H11] and sym-[6-(CO)-6-H-6,6-(PMe2Ph)2-9-(PPh3)-arachno-6-IrB9H11]
    1997, Vol. 62, Issue 8, pp. 1239–1253 [Abstract]
  • Bohumil Štíbr, Josef Holub, Tomáš Jelínek, Bohumír Grüner, Jiří Fusek, Zbyněk Plzák, Francesc Teixidor, Clara Viñas and John D. Kennedy
    A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12
    1997, Vol. 62, Issue 8, pp. 1229–1238 [Abstract]
  • Peter MacKinnon, Xavier L. R. Fontaine, John D. Kennedy and Paul A. Salter
    Polyhedral Azaborane Chemistry: NMR Parameters for the Unique Eight-Boron Polyhedral Species [(C2H5NH2)B8H11NHC2H5]
    1996, Vol. 61, Issue 12, pp. 1773–1782 [Abstract]
  • Tomáš Jelínek, Bohumil Štíbr and John D. Kennedy
    Nine-Vertex Polyhedral Monoazaborane Chemistry: Synthesis and NMR Characterization of exo-6-Ligand-arachno-4-azanonaboranes(11), 6-L-4-NB8H11
    1994, Vol. 59, Issue 10, pp. 2244–2252 [Abstract]
  • Tomáš Jelínek, Josef Holub, Bohumil Štíbr, Xavier L. R. Fontaine and John D. Kennedy
    Nine- and Eight-Vertex Polyhedral Dicarbaborane Chemistry: New arachno and hypho Dicarbaboranes from arachno-4,5-C2B7H13: Isolation and Characterization of the [arachno-4,5-C2B7H12]- and [hypho-7,8-C2B6H13]- Anions, and of the Neutral Ligand Derivatives exo-6-(MeNC)-arachno-4,5-C2B7H11 and exo-5-L-hypho-4,9-C2B7H13 (L = NMe3 and NEt3)
    1994, Vol. 59, Issue 7, pp. 1584–1595 [Abstract]
  • Josef Holub, John D. Kennedy and Bohumil Štíbr
    Nine-Vertex Polyhedral Monothiaborane Chemistry. The First nido Thianonaborane: Isolation and Characterization by NMR of the [nido-9-SB8H9]- Anion, and its Conversion to Compounds of the 6-L-arachno-4-SB8H10 Series (where L = SMe2 and Pyridine)
    1994, Vol. 59, Issue 2, pp. 367–373 [Abstract]
  • Jane H. Jones, Bohumil Štíbr, John D. Kennedy and Mark Thornton-Pett
    Ten-Vertex Polyhedral Monocarbaborane Chemistry. The Novel High-Yield Formation of the Ten-Vertex closo Compound [6-(PMe2Ph)-closo-1-CB9H9] from the Thermolysis of [8,8-(PMe2Ph)2-nido-8,7-PtCB9H11]
    1993, Vol. 58, Issue 12, pp. 2924–2935 [Abstract]
  • John D. Kennedy, Bohumil Štíbr, Tomáš Jelínek, Xavier L. R. Fontaine and Mark Thornton-Pett
    Eleven-Vertex Polyhedral Dicarbaplatinaborane Chemistry. Aspects of the Chemistry of Some closo-Structured {1,2,3-PtC2B8} Species and Some Related Compounds
    1993, Vol. 58, Issue 9, pp. 2090–2120 [Abstract]
  • Karl Nestor, Michael Murphy, Bohumil Štíbr, Trevor R. Spalding, Xavier L. R. Fontaine, Mark Thornton-Pett and John D. Kennedy
    Ten-Vertex Polyhedral Rhodadicarbaborane Chemistry. Molecular Structure, NMR Properties, and Cluster Dynamic Behaviour of [2,2,2-(PPh3)2H-closo-2,1,6-RhC2B7H9]
    1993, Vol. 58, Issue 7, pp. 1555–1568 [Abstract]
  • Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett, Eva Drdáková, Tomáš Jelínek and Jaromír Plešek
    Polyhedral Iridamonocarbaborane Chemistry. The Isolation and Characterisation of the Nine-Vertex closo-Type Species [(CO)(PPh3)2IrCB7H8] and the Partially Open Structures of Formally closo Nine-Vertex Clusters
    1992, Vol. 57, Issue 7, pp. 1439–1450 [Abstract]
  • Karl Nestor, Bohumil Štíbr, John D. Kennedy, Mark Thornton-Pett and Tomáš Jelínek
    Ten-Vertex Monocarbaborane Chemistry. A Convenient New Preparation of the [closo-1-CB9H10]- Anion and the Crystal and Molecular Structure of [(η5-C5Me5)2Ir2Cl3]+ [closo-1-CB9H10]-
    1992, Vol. 57, Issue 6, pp. 1262–1268 [Abstract]
  • Jaromír Plešek, Bohumil Štíbr, Xavier L. R. Fontaine, John D. Kennedy, Stanislav Heřmánek and Tomáš Jelínek
    Selective dismantling of closo-1,2-C2B10H12 to lower-cage dicarbaborane systems
    1991, Vol. 56, Issue 8, pp. 1618–1635 [Abstract]
  • Karl Nestor, Xavier L. R. Fontaine, John D. Kennedy, Bohumil Štíbr, Karel Baše and Mark Thornton-Pett
    Polyhedral organoiridaazaborane chemistry. The preparation of the eleven-vertex nido compound [9-Cl-8-(η5-C5Me5)-nido-8,7-IrNHB9H10] and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy
    1991, Vol. 56, Issue 8, pp. 1607–1617 [Abstract]
  • Bohumil Štíbr, Karel Baše, Tomáš Jelínek, Xavier L. R. Fontaine, John D. Kennedy and Mark Thornton-Pett
    Polyhedral platinadicarbaborane chemistry. The molecular structure and some NMR properties of [9,9-(PPh3)2-arachno-9,5,6-PtC2B7H11]
    1991, Vol. 56, Issue 3, pp. 646–656 [Abstract]