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Collect. Czech. Chem. Commun. 2006, 71, 215-236
https://doi.org/10.1135/cccc20060215

Synthesis and Coordination Behaviour of a Phosphanyl(vinyl)ferrocene

Petr Štěpnička* and Ivana Císařová

Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic

Crossref Cited-by Linking

  • Škoch Karel, Antala Jakub, Císařová Ivana, Štěpnička Petr: Synthesis and catalytic properties of palladium(ii) complexes with P,π-chelating ferrocene phosphinoallyl ligands and their non-tethered analogues. Dalton Trans. 2024, 53, 8722. <https://doi.org/10.1039/D4DT00961D>
  • Vosáhlo Petr, Schulz Jiří, Škoch Karel, Císařová Ivana, Štěpnička Petr: Synthesis and characterisation of palladium(ii) complexes with hybrid phosphinoferrocene ligands bearing additional O-donor substituents. New J. Chem. 2019, 43, 4463. <https://doi.org/10.1039/C9NJ00298G>
  • Vosáhlo Petr, Císařová Ivana, Štěpnička Petr: Comparing the asymmetric dppf-type ligands with their semi-homologous counterparts. Journal of Organometallic Chemistry 2018, 860, 14. <https://doi.org/10.1016/j.jorganchem.2018.01.009>
  • Škoch Karel, Císařová Ivana, Uhlík Filip, Štěpnička Petr: Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(ii) complexes: synthesis of simple coordination compounds vs. preparation of P-chelated insertion products and Fischer-type carbenes. Dalton Trans. 2018, 47, 16082. <https://doi.org/10.1039/C8DT03564D>
  • Bárta Ondřej, Císařová Ivana, Štěpnička Petr: Synthesis, Palladium(II) Complexes, and Catalytic Use of a Phosphanylferrocene Ligand Bearing a Guanidinium Pendant. Eur J Inorg Chem 2017, 2017, 489. <https://doi.org/10.1002/ejic.201601262>
  • Zábranský Martin, Machara Aleš, Císařová Ivana, Štěpnička Petr: Palladium(II) Complexes of Homologated Ferrocene Phosphanylether and Thioether Ligands. Eur J Inorg Chem 2017, 2017, 4850. <https://doi.org/10.1002/ejic.201701057>
  • Škoch Karel, Císařová Ivana, Štěpnička Petr: Phosphinoferrocene Ureas: Synthesis, Structural Characterization, and Catalytic Use in Palladium-Catalyzed Cyanation of Aryl Bromides. Organometallics 2015, 34, 1942. <https://doi.org/10.1021/acs.organomet.5b00197>
  • Škoch Karel, Císařová Ivana, Štěpnička Petr: 1′-(Diphenylphosphino)-1-cyanoferrocene: A Simple Ligand with Complicated Coordination Behavior toward Copper(I). Inorg. Chem. 2014, 53, 568. <https://doi.org/10.1021/ic4026848>
  • Štěpnička Petr, Císařová Ivana: Selective borane reduction of phosphinoferrocene carbaldehydes to phosphinoalcohol–borane adducts. The coordination behaviour of 1-(diphenylphosphino)- 1′-(methoxymethyl)ferrocene, a new ferrocene O,P-hybrid donor prepared from such an adduct. Dalton Trans. 2013, 42, 3373. <https://doi.org/10.1039/C2DT32511J>
  • Shan Xiao-Chen, Jiang Fei-Long, Chen Lian, Wu Ming-Yan, Pan Jie, Wan Xiu-Yan, Hong Mao-Chun: Using cuprophilicity as a multi-responsive chromophore switching color in response to temperature, mechanical force and solvent vapors. J. Mater. Chem. C 2013, 1, 4339. <https://doi.org/10.1039/c3tc30482e>
  • Štěpnička Petr, Zábranský Martin, Císařová Ivana: An Alternative Preparation of 1‐(N,N‐Dimethylaminomethyl)‐1′‐(diphenylphosphanyl)ferrocene: Synthesis and Structural Characterization of AuI and PdII Complexes with this Hybrid Ligand. ChemistryOpen 2012, 1, 71. <https://doi.org/10.1002/open.201200004>
  • Schulz Jiří, Císařová Ivana, Štěpnička Petr: Phosphinoferrocene Amidosulfonates: Synthesis, Palladium Complexes, and Catalytic Use in Pd-Catalyzed Cyanation of Aryl Bromides in an Aqueous Reaction Medium. Organometallics 2012, 31, 729. <https://doi.org/10.1021/om2011529>
  • Štěpnička Petr, Solařová Hana, Císařová Ivana: Synthesis and structural characterization of 1′-(diphenylphosphino)ferrocene-1-carboxamide, its corresponding hydrazide, some heterocycles derived from the hydrazide and palladium(II) complexes with these functional phosphinoferrocene ligands. Journal of Organometallic Chemistry 2011, 696, 3727. <https://doi.org/10.1016/j.jorganchem.2011.08.043>
  • Perruchas Sandrine, Tard Cédric, Le Goff Xavier F., Fargues Alexandre, Garcia Alain, Kahlal Samia, Saillard Jean-Yves, Gacoin Thierry, Boilot Jean-Pierre: Thermochromic Luminescence of Copper Iodide Clusters: The Case of Phosphine Ligands. Inorg. Chem. 2011, 50, 10682. <https://doi.org/10.1021/ic201128a>
  • Tauchman Jiří, Císařová Ivana, Štěpnička Petr: Chiral phosphinoferrocene carboxamides with amino acid substituents as ligands for Pd-catalysed asymmetric allylic substitutions. Synthesis and structural characterisation of catalytically relevant Pd complexes. DALTON T 2011, 40, 11748. <https://doi.org/10.1039/c1dt11230a>
  • Štěpnička Petr, Solařová Hana, Lamač Martin, Císařová Ivana: Preparation of phosphinoferrocene carboxamides from isocyanates. Synthesis and structural characterisation of palladium(II) and platinum(II) complexes with 1′-(diphenylphosphino)-1-(N-phenylcarbamoyl)ferrocene. Journal of Organometallic Chemistry 2010, 695, 2423. <https://doi.org/10.1016/j.jorganchem.2010.07.013>
  • Štěpnička Petr, Schulz Jiří, Klemann Thorsten, Siemeling Ulrich, Císařová Ivana: Synthesis, Structural Characterization, and Catalytic Evaluation of Palladium Complexes with Homologous Ferrocene-Based Pyridylphosphine Ligands. Organometallics 2010, 29, 3187. <https://doi.org/10.1021/om100339p>
  • Schulz Jiří, Císařová Ivana, Štěpnička Petr: Preparation, coordination properties and catalytic use of 1′-(diphenylphosphanyl)-1-ferrocenecarboxamides bearing 2-hydroxyethyl pendant groups. Journal of Organometallic Chemistry 2009, 694, 2519. <https://doi.org/10.1016/j.jorganchem.2009.04.007>
  • Tauchman Jiří, Císařová Ivana, Štěpnička Petr: Phosphinoferrocenyl Carboxamides Bearing Glycine Pendant Groups: Synthesis, Palladium(II) Complexes, and Catalytic Use in Polar and Aqueous Reaction Media. Organometallics 2009, 28, 3288. <https://doi.org/10.1021/om900209j>
  • Štěpnička Petr, Císařová Ivana: Synthesis, structural characterisation and electrochemistry of bis[(diphenylphosphino)ferrocene]diruthenium complexes [Ru2(μ-RCO2)2(CO)4(FcPPh2)2] (R = H and Me). Collect. Czech. Chem. Commun. 2009, 74, 799. <https://doi.org/10.1135/cccc2009003>
  • McAdam C. John, Robinson Brian H., Simpson Jim: Deamination of 1-aminoethylferrocene and the crystal structure of ethenylferrocene. Inorg Chim Ada 2008, 361, 2172. <https://doi.org/10.1016/j.ica.2007.10.035>
  • Štěpnička Petr: Preparation, structural characterisation and electrochemical properties of iron(0) and tungsten(0) carbonyl complexes with 1-(diphenylphosphanyl)-1′-vinylferrocene and 1-(diphenylphosphanyl)-1′-(dimethylvinylsilyl)ferrocene as P-monodentate ligands. Journal of Organometallic Chemistry 2008, 693, 297. <https://doi.org/10.1016/j.jorganchem.2007.10.056>
  • Štěpnička Petr, Lamač Martin, Císařová Ivana: Planar chiral alkenylferrocene phosphanes: Preparation, structural characterisation and catalytic use in asymmetric allylic alkylation. Journal of Organometallic Chemistry 2008, 693, 446. <https://doi.org/10.1016/j.jorganchem.2007.11.016>
  • Štěpnička Petr, Schulz Jiří, Císařová Ivana, Fejfarová Karla: Synthesis, Characterization and Catalytic Utilization of a Ferrocene Diamidodiphosphane. Collect. Czech. Chem. Commun. 2007, 72, 453. <https://doi.org/10.1135/cccc20070453>