Collect. Czech. Chem. Commun. 2007, 72, 492-502
https://doi.org/10.1135/cccc20070492

Zinc and Cobalt(II) Complexes of Tripodal Nitrogen Ligands of the Tris[2-substituted Imidazol-4(5)-yl]phosphane Type. Biomimetic Hydrolysis of an Activated Ester

Peter C. Kunz* and Wolfgang Kläui

Heinrich-Heine-Universität, Institut für Anorganische Chemie, Universitätsstr. 1, D-40225 Düsseldorf, Germany

References

1a. Kaim W., Schwederski B.: Bioanorganische Chemie, 3rd ed. B. G. Teubner, Stuttgart 2004.
1b. Bertini I., Sigel A., Sigel H. (Eds): Handbook on Metalloproteins. Marcel Dekker, New York 2001.
2. Burzlaff N. in: Concepts and Models in Bioinorganic Chemistry (H.-B. Kraatz and N. Metzler-Nolte, Eds), Chap. 17; and references therein. Wiley-VCH, Weinheim 2006.
3. Trofimenko S.: Scorpionates – The Coordination Chemistry of Polypyrazolylborate Ligands; and references therein. Imperial College Press, London 1999.
4a. Parkin G.: Chem. Rev. 2004, 104, 699. <https://doi.org/10.1021/cr0206263>
4b. Parkin G.: J. Chem. Soc., Chem. Commun. 2000, 1971. <https://doi.org/10.1039/b004816j>
5a. Ibrahim M., Perez Olmo C., Tekeste T., Seebacher J., He G., Calvo M. A. J., Boehmerle K., Steinfeld G., Brombacher H., Vahrenkamp H.: Inorg. Chem. 2006, 45, 7493. <https://doi.org/10.1021/ic060752f>
5b. Perez Olmo C., Boehmerle K., Steinfeld G., Vahrenkamp H.: Eur. J. Inorg. Chem. 2006, 3869. <https://doi.org/10.1002/ejic.200600382>
5c. Vahrenkamp H.: Acc. Chem. Res. 1999, 32, 589. <https://doi.org/10.1021/ar9703185>
6a. Kimblin C., Allen W. E., Parkin G.: J. Chem. Soc., Chem. Commun. 1995, 1813. <https://doi.org/10.1039/c39950001813>
6b. Kimblin C., Murphy V. J., Parkin G.: J. Chem. Soc., Chem. Commun. 1996, 235. <https://doi.org/10.1039/cc9960000235>
6c. Kimblin C., Bridgewater B. M., Churchill D. G., Parkin G.: J. Chem. Soc., Dalton Trans. 2000, 2191. <https://doi.org/10.1039/b002894k>
6d. Kimblin C., Murphy V. J., Hascall T., Bridgewater B. M., Bonanno J. B., Parkin G.: Inorg. Chem. 2000, 39, 967. <https://doi.org/10.1021/ic990682v>
6e. Kläui W., Piefer C., Rheinwald G., Lang H.: Eur. J. Inorg. Chem. 2000, 7, 1549. <https://doi.org/10.1002/1099-0682(200007)2000:7<1549::AID-EJIC1549>3.0.CO;2-#>
7a. Huguet J., Brown R. S.: J. Am. Chem. Soc. 1980, 102, 7572. <https://doi.org/10.1021/ja00545a034>
7b. Read R. J., James M. N. G.: J. Am. Chem. Soc. 1981, 103, 6947. <https://doi.org/10.1021/ja00413a030>
7c. Brown R. S., Curtis N. J., Huguet J.: J. Am. Chem. Soc. 1981, 103, 6953. <https://doi.org/10.1021/ja00413a031>
7d. Brown R. S., Salmon D., Curtis N. J., Kusuma S.: J. Am. Chem. Soc. 1982, 104, 3188. <https://doi.org/10.1021/ja00375a043>
7e. Brown R. S., Zamkani M., Cocho J. L.: J. Am. Chem. Soc. 1984, 106, 5222. <https://doi.org/10.1021/ja00330a031>
7f. Ball R. G., Brown R. S., Cocho J. L.: Inorg. Chem. 1984, 23, 2315. <https://doi.org/10.1021/ic00183a021>
8. Kunz P. C., Reiss G. J., Frank W., Kläui W.: Eur. J. Inorg. Chem. 2003, 3945. <https://doi.org/10.1002/ejic.200300228>
9. Breslow R., Hunt J. T., Smiley R., Tarnowski T.: J. Am. Chem. Soc. 1983, 105, 5337. <https://doi.org/10.1021/ja00354a025>
10. Bell R. A., Lock C. J. L., Scholten C., Valliant J. F.: Inorg. Chim. Acta 1998, 137. <https://doi.org/10.1016/S0020-1693(97)06039-8>
11. The poor solubility of the zinc complex of 2b is not understood, especially as the solubility of the corresponding Co(II) complex is good. We have not been able to recrystallise 4.
12. Kremer-Aach A., Kläui W., Bell R., Strerath A., Wunderlich H., Mootz D.: Inorg. Chem. 1997, 36, 1552. <https://doi.org/10.1021/ic961434r>
13. Trofimenko S., Calabrese J. C., Thompson J. S.: Inorg. Chem. 1987, 26, 1507. <https://doi.org/10.1021/ic00257a010>
14. Akiyama M., Hara Y., Tanabe M.: J. Chem. Soc., Perkin Trans. 2 1978, 288. <https://doi.org/10.1039/p29780000288>
15. Yu Q., Kandegedara A., Xu Y., Rorabacher D. B.: Anal. Biochem. 1997, 253, 50. <https://doi.org/10.1006/abio.1997.2349>
16. Bates R. G., Paabo M., Robinson R. A.: J. Phys. Chem. 1963, 67, 1833. <https://doi.org/10.1021/j100803a022>