Collect. Czech. Chem. Commun.
2008, 73, 1612-1622
https://doi.org/10.1135/cccc20081612
Compounds R1R2EMMe3 (E = P, As; M = Si, Sn) - Convenient and Versatile Reagents for the Syntheses of Tertiary (Fluoroaryl)phosphanes and -arsanes
Leonid I. Goryunova, Joseph Grobeb,* and Vitalii D. Shteingartsa,*
a Novosibirsk Institute of Organic Chemistry, Siberian Division of RAS, Lavrentiev Ave. 9, 630090 Novosibirsk, Russia
b Institut für Anorganische und Analytische Chemie der Westfälischen Wilhelms-Universität, Corrensstrasse 36, D-48149 Münster, Germany
Abstract
Synthetic and mechanistic aspects of nucleophilic replacement of fluorine in fluorobenzenes, fluoropyridines and fluoroquinolines by phosphanyl and arsanyl groups via their reactions with R1R2EMMe3 (E = P, As; M = Si, Sn; R1, R2 = Me, i-Pr, t-Bu, Ph, etc.) reagents are considered.
Keywords: Arsanes; Phosphanes; Phosphines; Polyfluoroarenes; Fluorinated ligands; Fluoropyridines; Rhodium complexes.
References: 25 live references.
