Collect. Czech. Chem. Commun.
2008, 73, 413-423
https://doi.org/10.1135/cccc20080413
Fluids of Hard Nonspherical Molecules. I. Higher Virial Coefficients
Magda Francová, Jiří Kolafa*, Pavel Morávek, Stanislav Labík and Anatol Malijevský
Department of Physical Chemistry, Institute of Chemical Technology, Prague, 166 28 Prague 6, Czech Republic
This article is part of serial Fluids of Hard Nonspherical Molecules.
Abstract
Virial coefficients of hard prolate spherocylinders and hard homonuclear diatomics are calculated up to the ninth for a number of molecule elongations. The results are fitted to an analytical formula as a function of the elongation.
Keywords: Virial coefficient; Hard prolate spherocylinder; Hard homonuclear diatomics; Hard dumbbell; Thermodynamics; Equation-of-state.
References: 29 live references.
