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Collect. Czech. Chem. Commun. 2011, 76, 177-191
https://doi.org/10.1135/cccc2010155
Published online 2011-02-15 10:37:41

Dehydrocoupling of SiMe2H substituents in permethylated zirconocene complexes

Jiří Pinkasa, Róbert Gyepesb,c, Ivana Císařováb, Jiří Kubištaa, Karel Macha and Michal Horáčeka,*

a J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i., Dolejškova 3, 182 23 Prague 8, Czech Republic
b Department of Inorganic Chemistry, Charles University, Hlavova 2030, 128 40 Prague 2, Czech Republic
c Present address: J. Selye University, Pedagogical Faculty, Bratislavská cesta 3322, 945 01 Komárno, Slovak Republic,

Crossref Cited-by Linking

  • Burlakov Vladimir V., Lyakhovetsky Yury I.: Acetylene complexes of metallocenes of titanium, zirconium and hafnium. I. Synthesis, structure, and spectral characteristics. Coordination Chemistry Reviews 2023, 493, 215252. <https://doi.org/10.1016/j.ccr.2023.215252>
  • Pinkas Jiří, Císařová Ivana, Gyepes Róbert, Kubišta Jiří, Mach Karel, Horáček Michal: Substituent effects in reduction-induced synthesis of ansa-titanocenes. Transition Met Chem 2016, 41, 143. <https://doi.org/10.1007/s11243-015-0006-3>
  • Pinkas Jiří, Lamač Martin: Transformations of functional groups attached to cyclopentadienyl or related ligands in group 4 metal complexes. Coordination Chemistry Reviews 2015, 296, 45. <https://doi.org/10.1016/j.ccr.2015.03.007>
  • Horáček Michal, Gyepes Róbert, Císařová Ivana, Pinkas Jiří, Kubišta Jiří, Lamač Martin: Intramolecular activation of a pendant nitrile group in Ti and Zr metallocene complexes. Journal of Organometallic Chemistry 2015, 787, 56. <https://doi.org/10.1016/j.jorganchem.2015.04.021>
  • Godemann Christian, Spannenberg Anke, Beweries Torsten: Crystal structure of 1,1,2,2-tetramethyl-1,2-bis(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)disilane. Acta Crystallogr E Cryst Commun 2015, 71, o888. <https://doi.org/10.1107/S2056989015019891>
  • Strašák Tomáš, Sýkora Jan, Lamač Martin, Kubišta Jiří, Horáček Michal, Gyepes Róbert, Pinkas Jiří: Reactivity of a Titanocene Pendant Si–H Group toward Alcohols. Unexpected Formation of Siloxanes from the Reaction of Hydrosilanes and Ph3COH Catalyzed by B(C6F5)3. Organometallics 2013, 32, 4122. <https://doi.org/10.1021/om400253g>